Synthesis, characterisation and reactivity of the first diphosphaalkyne

被引：20

作者：

Brym, M ^{[1
]}

Jones, C ^{[1
]}

机构：

[1] Cardiff Univ, Dept Chem, Cardiff CF10 3TB, S Glam, Wales

来源：

DALTON TRANSACTIONS | 2003年 / 19期

关键词：

D O I：

10.1039/b309061b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first diphosphaalkyne, P=CC(C6H4)(3)CC=P, has been synthesised and structurally characterised; its reaction with [Pt(C2H4)(PPh3)(2)] affords the complex, [{(PPh3)(2)Pt} (2){mu-eta(2):eta(2)-P=CC(C6H4)(3)CC=P}], whilst its treatment with [RuHCl(CO)(PPh3)(3)] yields the bis-ruthenium phosphaalkenyl complex, [{(PPh3)(2)(CO) ClRu}(2){mu-P=C(H)C( C6H4)(3)CC(H)=P}].

引用

页码：3665 / 3667

页数：3

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