New generation of supported Ziegler-type catalysts for polyethylene production

被引：9

作者：

Mikenas, T. B. ^{[1
]}

Zakharov, V. A. ^{[1
]}

Nikitin, V. E. ^{[1
]}

Echevskaya, L. G. ^{[1
]}

Matsko, M. A. ^{[1
]}

机构：

[1] Boreskov Inst Catalysis SB RAS, Novosibirsk, Russia

来源：

RUSSIAN JOURNAL OF APPLIED CHEMISTRY | 2010年 / 83卷 / 12期

关键词：

TITANIUM-MAGNESIUM CATALYSTS; NATTA CATALYSTS; ETHYLENE; POLYMERIZATION; COPOLYMERIZATION;

D O I：

10.1134/S1070427210120281

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

On the basis of new methods of synthesis of magnesium-containing carriers with the use of soluble organomagnesium compounds a wide spectrum of supported titanium-magnesium and vanadium-magnesium catalysts of various composition with controllable optimal morphology for obtaining versatile brands of polyethylene by suspension and gas-phase methods was elaborated. The usage of various modifications of these catalysts allows production of high amount (up to 1000 kg/g Ti) of polyethylene of high, medium, and low density with narrow and wide molecular weight distribution (including bimodal) as well as different brands of polyethylene ultrahigh molecular weight.

引用

页码：2210 / 2219

页数：10

共 20 条

[1] Molecular mass characteristics of polyethylene produced with supported vanadium-magnesium catalysts [J].