A Double-Tailed Fluorescent Surfactant with a Hexavanadate Cluster as the Head Group

被引：181

作者：

Yin, Panchao ^{[1
,2
]}

Wu, Pingfan ^{[2
,3
]}

Xiao, Zicheng ^{[2
]}

Li, Dong

Bitterlich, Emily ^{[1
]}

Zhang, Jin ^{[2
]}

Cheng, Peng ^{[1
]}

Vezenov, Dmitri V. ^{[1
]}

Liu, Tianbo ^{[1
]}

Wei, Yongge ^{[2
]}

机构：

[1] Lehigh Univ, Dept Chem, Bethlehem, PA 18015 USA

[2] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China

[3] Hubei Univ Technol, Sch Chem & Environm Engn, Wuhan 430068, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 11期

关键词：

hybrid materials; luminescence; polyoxometalates; self-assembly; surfactants; STRUCTURAL-CHARACTERIZATION; HYBRID; TRANSITION; POLYMERS; SYSTEMS; SIZES; CORE;

D O I：

10.1002/anie.201006144

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Blue rinse: A hybrid surfactant that comprises a hexavanadate cluster and two C18 alkyl chains shows unexpected blue luminescence (see picture). The luminescence arises from the interaction between the counterions and the hexavanadate clusters, and varies with the type of counterions. This behavior was confirmed by studying the self-assembly of the hybrids with various counterions in different solvents. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：2521 / 2525

页数：5

共 25 条

[1] RETRACTED: A late-transition metal oxo complex: K7Na9[O=PtIV(H2O)L2]. L = [PW9O34]9- (Retracted Article) [J].

Anderson, TM ;

Neiwert, WA ;

Kirk, ML ;

Piccoli, PMB ;

Schultz, AJ ;

Koetzle, TF ;

Musaev, DG ;

Morokuma, K ;

Cao, R ;

Hill, CL .

SCIENCE, 2004, 306 (5704) :2074-2077

[2]

[Anonymous], 2010, ANGEW CHEM INT EDIT, DOI [DOI 10.1002/ANGE.200902483, DOI 10.1002/ange.200902483]

[3]

[Anonymous], 2003, ANGEW CHEM, V115, P1195

[4] A mixed-valence polyoxovanadate(III,IV) cluster with a calixarene cap exhibiting ferromagnetic V(III)-V(IV) interactions [J].

Aronica, Christophe ;

Chastanet, Guillaume ;

Zueva, Ekaterina ;

Borshch, Serguei A. ;

Clemente-Juan, Juan M. ;

Luneau, Dominique .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (07) :2365-2371

[5] A basket tetradecavanadate cluster with blue luminescence [J].

Chen, L ;

Jiang, FL ;

Lin, ZZ ;

Zhou, YF ;

Yue, CY ;

Hong, MC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (24) :8588-8589

[6] COORDINATION-COMPOUNDS OF POLYOXOVANADATES WITH A HEXAMETALATE CORE - CHEMICAL AND STRUCTURAL CHARACTERIZATION OF [V(V)6O13((OCH2)3CR(2]2-, [V(V)6O11(OH)2((OCH2)3CR(2], [V(IV)4V(V)2O9(OH)4((OCH2)3CR(2]2-, AND [V(IV)6O7(OH)6((OCH2)3CR(2]2- [J].

CHEN, Q ;

GOSHORN, DP ;

SCHOLES, CP ;

TAN, XL ;

ZUBIETA, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (12) :4667-4681

[7] Neutral and cationic VIV/VV mixed-valence alkoxo-polyoxovanadium clusters [V6O7(OR)12]n+ (R = -CH3, -C2H5):: Structural, cyclovoltammetric and IR-spectroscopic investigations on mixed valency in a hexanuclear core [J].

Daniel, C ;

Hartl, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (40) :13978-13987

[8] A Mixed-Valence VIV/VV Alkoxo-polyoxovanadium Cluster Series [V6O8(OCH3)11]n+/-: Exploring the Influence of a μ-Oxo Ligand in a Spin Frustrated Structure [J].

Daniel, Charles ;

Hartl, Hans .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (14) :5101-5114

[9] A coordination network that catalyzes O2-based oxidations [J].

Han, Jong Woo ;

Hill, Craig L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (49) :15094-+

[10] Redox-active coordination polymers from esterified hexavanadate units and divalent metal cations [J].

Han, Jong Woo ;

Hardcastle, Kenneth I. ;

Hill, Craig L. .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, 13 (13) :2598-2603

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