Recent developments in the coordination and organometallic chemistry of Klaui oxygen tripodal ligands

被引：47
|
作者：
Leung, Wa-Hung
Zhang, Qian-Feng
Yi, Xiao-Yi
机构：
[1] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China
[2] Anhui Univ Technol, Dept Appl Chem, Maanshan 243002, Anhui, Peoples R China
来源：
COORDINATION CHEMISTRY REVIEWS | 2007年 / 251卷 / 17-20期
关键词：
oxygen ligand; tripodal ligand; metal complex; cluster;
D O I：
10.1016/j.ccr.2006.11.019
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The Klaui oxygen tripodal ligands [(eta(5)-C5H5)Co{P(O)(OR)(2)}(3)](-) (L-OR(-) where R = alkyl group), which have been recognized as oxygen analogues of cyclopentadienyl, can form stable complexes with a range of main group and transition metal ions. This review reports on the recent developments in the coordination and organometallic chemistry of the Klaui tripodal ligands. Special attention will be paid to polynuclear M-L-OEt (M = Ti, Zr) oxo and hydroxo compounds that may serve as models for group 4 metal aqua ions. (C) 2006 Elsevier B.V. All rights reserved.
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页码：2266 / 2279
页数：14
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