Construction of zinc-organic frameworks by flexible aliphatic dicarboxylates plus 2-(1H-imidazolyl-1-methyl)-1H-benzimidazole ligand

被引：14
作者：
Huang, Qiuying [1 ,2 ]
Wang, Xiuxiu [2 ]
Li, Ting [2 ]
Meng, Xiangru [2 ]
机构：
[1] Henan Polytech Inst, Dept Chem Engn, Nanyang, Peoples R China
[2] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450052, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2015年 / 68卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Zn(II)-complex; 2-(1H-imidazolyl-1-ylmethyl)-1H-benzimidazole; Aliphatic dicarboxylates; Photoluminescence property; Thermostability; COPPER(II) MALONATE COMPLEXES; CRYSTAL-STRUCTURES; COORDINATION POLYMERS; FLUORESCENT PROPERTIES; STRUCTURAL VARIATION; MAGNETIC-PROPERTIES; PLANAR NETWORKS; MIXED-LIGANDS; ARCHITECTURES; 2-(1H-IMIDAZOLE-1-YLMETHYL)-1H-BENZIMIDAZOLE;
D O I：
10.1080/00958972.2014.984702
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three new Zn(II) complexes, [Zn(ox)(imb)] (1), [Zn-2(mal)(2)(imb)(2)] (2), and [Zn(suc)(imb)]H2O (3) (imb=2-(1H-imidazolyl-1-methyl)-1H-benzimidazole, H(2)ox=oxalic acid, H(2)mal=malonic acid, H(2)suc=succinic acid), have been synthesized and structurally characterized. Complex 1 is a 3-D framework with a 4-connected diamond topology with the topological notation of 6(6). Complex 2 exhibits 2-D layers with (6,3) networks. Complex 3 displays a 3-D framework constructed through unusual 2-D3-D parallel interpenetration of corrugated 2-D (6,3) networks. IR spectra, PXRD patterns, thermogravimetric curves, and photoluminescence spectra are addressed.
引用
收藏
页码：88 / 105
页数：18
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