Electron transfer reactions in micellar systems

被引:24
作者
Prado-Gotor, R [1 ]
Jiménez, R [1 ]
Pérez-Tejeda, P [1 ]
López-Cornejo, P [1 ]
López-López, M [1 ]
Sánchez, A [1 ]
Muriel-Delgado, F [1 ]
Sánchez, F [1 ]
机构
[1] Univ Seville, Fac Quim, Dept Quim Fis, Seville 41012, Spain
关键词
electron tranfer; micellar system; Marcus' Theory;
D O I
10.3184/007967400103165173
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The influence of micelles on electron transfer processes is reviewed. The micelles modify the rate of electron transfer reactions by producing changes in all the relevant parameters controlling this rate; that is, through modification of the reorganization free energy, the reaction free energy, the nuclear dynamics and the strength of the coupling between the donor and the acceptor. Applications of studies on electron transfer reactions in micellar systems in different fields are presented.
引用
收藏
页码:371 / 407
页数:37
相关论文
共 129 条
[1]  
Albery J., 1975, ELECT KINETICS
[2]   LASER PHOTOIONIZATION OF PHENOTHIAZINE IN ALCOHOLIC AND AQUEOUS MICELLAR SOLUTION - ELECTRON-TRANSFER FROM TRIPLET-STATES TO METAL-ION ACCEPTORS [J].
ALKAITIS, SA ;
BECK, G ;
GRATZEL, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (20) :5723-5729
[3]   ONE-ELECTRON REDOX POTENTIALS AND RATE OF ELECTRON-TRANSFER IN AQUEOUS MICELLAR SOLUTION - PARTIALLY SOLUBILIZED QUINONES [J].
ALMGREN, M ;
GRIESER, F ;
THOMAS, JK .
JOURNAL OF PHYSICAL CHEMISTRY, 1979, 83 (25) :3232-3236
[4]  
ALMGREN M, 1991, KINETICS CATALYSIS M, P63
[5]   Luminescence quenching in supramolecular systems: A comparison of DNA- and SDS micelle-mediated photoinduced electron transfer between metal complexes [J].
Arkin, MR ;
Stemp, EDA ;
Turro, C ;
Turro, NJ ;
Barton, JK .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (09) :2267-2274
[6]   REACTIONS OF RADICALS WITH LECITHIN BILAYERS [J].
BARBER, DJW ;
THOMAS, JK .
RADIATION RESEARCH, 1978, 74 (01) :51-65
[7]   LASER-INDUCED PHOTOIONIZATION IN LIPID AGGREGATES [J].
BARBER, DJW ;
MORRIS, DAN ;
THOMAS, JK .
CHEMICAL PHYSICS LETTERS, 1976, 37 (03) :481-484
[8]   COUNTERION CONTRIBUTION TO THE DIELECTRIC SPECTRUM OF AQUEOUS-SOLUTIONS OF IONIC SURFACTANT MICELLES [J].
BARCHINI, R ;
POTTEL, R .
JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (32) :7899-7905
[9]   Theory of diffusion-assisted reactions on micelle surfaces: Photoinduced electron transfer followed by back transfer [J].
Barzykin, AV ;
Seki, K ;
Tachiya, M .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (43) :9156-9160
[10]  
Barzykin AV, 1996, HETEROGEN CHEM REV, V3, P105, DOI 10.1002/(SICI)1234-985X(199606)3:2<105::AID-HCR56>3.0.CO