Titanium dioxide/zinc indium sulfide hetero-junction: An efficient photoanode for the dye-sensitized solar cell

被引:16
作者
Hou, Wenjing [1 ,2 ]
Xiao, Yaoming [1 ,2 ]
Han, Gaoyi [1 ,2 ]
Zhang, Ying [1 ,2 ]
Chang, Yunzhen [1 ,2 ]
机构
[1] Shanxi Univ, Inst Mol Sci, Innovat Ctr Chem & Mol Sci, Taiyuan 030006, Peoples R China
[2] Shanxi Univ, Key Lab Chem Biol & Mol Engn, Educ Minist, Taiyuan 030006, Peoples R China
基金
中国国家自然科学基金;
关键词
TiO2/ZnIn2S4; Hetero-junction; Photoanode; Dye-sensitized solar cell; HIGHLY EFFICIENT; THIN-FILMS; TIO2; ZNIN2S4; DYNAMICS; DEGRADATION; PERFORMANCE; ARRAYS; LAYER;
D O I
10.1016/j.jpowsour.2016.08.063
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A facile strategy is developed for the fabrication of titanium dioxide/zinc indium sulfide (TiO2/ZnIn2S4) hetero-junction photoanode with an adjustable ZnIn2S4 doping content and application in the dye sensitized solar cell (DSSC). Comparing to the pure TiO2, TiO2/ZnIn2S4 hetero-junction materials demonstrate an enhanced light utilizing efficiency, a reduced recombination rate of electron-hole pairs, and an accelerated migration process of photoinduced electrons. Due to above merits, DSSC based on TiO2/ZnIn2S4 hetero-junction photoanode achieves a greatly enhanced short-circuit current density, leading to an improved photoelectric conversion efficiency of 8.09% under full sunlight illumination (100 mW cm(-2), AM 1.5 G), which is almost 14.43% higher than that of the pure TiO2-based DSSC (7.07%). (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:578 / 585
页数:8
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