Micellar Solutions of a Symmetrical Amphiphilic ABA Triblock Copolymer with a Temperature-Responsive Shell

被引：10
作者：
Jain, A. [1 ]
Kulkarni, A. [1 ]
Koumba, A. M. Bivigou [2 ]
Wang, W. [1 ]
Busch, P. [3 ]
Laschewsky, A. [2 ]
Mueller-Buschbaum, P. [1 ]
Papadakis, C. M. [1 ]
机构：
[1] Tech Univ Munich, Phys Dept E13, James Franck Str 1, D-85747 Garching, Germany
[2] Univ Potsdam, Inst Chemie, D-14476 Golm, Germany
[3] Forschungszentrum Julich, FRM 2, Julich Ctr Neutron Sci, D-85747 Garching, Germany
来源：
POLYMER NETWORKS: SYNTHESIS, PROPERTIES, THEORY AND APPLICATIONS | 2010年 / 291-292卷
关键词：
amphiphiles; colloids; dynamic light scattering; micelles; small-angle neutron scattering; stimuli-sensitive polymers; ANGLE NEUTRON-SCATTERING; VOLUME-PHASE-TRANSITION; POLY N-ISOPROPYLACRYLAMIDE; X-RAY-SCATTERING; LIGHT-SCATTERING; POLY(N-ISOPROPYLACRYLAMIDE) CHAINS; CONFORMATIONAL-CHANGE; MICROGEL PARTICLES; DIBLOCK COPOLYMERS; BLOCK-COPOLYMERS;
D O I：
10.1002/masy.201050526
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
We have studied the thermal behavior of an ABA triblock copolymer having short, deuterated polystyrene end-blocks and a longer poly(N-isopropyl acrylamide) middle block, the latter exhibiting a lower critical solution temperature. The collapse of the micelles was investigated using dynamic light scattering. Small-angle neutron scattering with contrast matching allowed us to quantify the core-shell structure of the micelles as well as their correlations as a function of temperature.
引用
收藏
页码：221 / +
页数：3
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