Structure, infrared and Raman spectroscopic studies of newly synthetic AII(SbV0.50FeIII0.50)(PO4)2 (A = Ba, Sr, Pb) phosphates with yavapaiite structure

被引：9

作者：

Aatiq, Abderrahim ^{[1
]}

Tigha, My Rachid ^{[1
]}

Fakhreddine, Rachid ^{[1
]}

Bregiroux, Damien ^{[2
]}

Wallez, Gilles ^{[3
,4
]}

机构：

[1] Univ HassanII Casablanca, Fac Sci Ben MSik, Dept Chim, Lab Physicochim Mat Appl, Ave Idriss El Harti,BP 7955, Casablanca, Morocco

[2] Univ Paris 06, Sorbonne Univ, CNRS, Coll France,Lab Chim Matiere Condensee Paris, 11 Pl Marcelin Berthelot, F-75005 Paris, France

[3] CNRS, Chim Paris Tech, Paris Sci & Lettres PSL UMR8247, IRCP, 11 Rue Pierre & Marie Curie, F-75005 Paris, France

[4] Univ Paris 06, Sorbonne Univ, F-75252 Paris 05, France

来源：

SOLID STATE SCIENCES | 2016年 / 58卷

关键词：

Antimony and iron phosphate; Yavapaiite structure; Raman and IR spectroscopy; Rietveld analysis; CRYSTAL-STRUCTURE; ZIRCONIUM DIORTHOPHOSPHATE; PHASE-TRANSITIONS; THERMAL-EXPANSION; NASICON PHASES; CAZR(PO4)(2); CHEMISTRY; CHERALITE; BARIUM; SBOPO4;

D O I：

10.1016/j.solidstatesciences.2016.05.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and structural study of three new A(II)((Sb0.5Fe0.5III)-Fe-V)(PO4)(2) (A=Ba, Sr, Pb) phosphates belonging to the A-Sb-Fe-P-O system were reported here for the first time. Structures of [Ba], [Sr] and [Pb] compounds, obtained by solid state reaction in air atmosphere, were determined at room temperature from X-ray powder diffraction using the Rietveld method. Ba-II(Sb(V)0.5Fe(III)0.5)(PO4)(2) features the yavapaiite-type structure, with space group C2/m, Z = 2 and a = 8.1568(4) angstrom; b = 5.1996(3) angstrom c = 7.8290(4) angstrom; beta = 94.53(1)degrees. A(II)((Sb0.5Fe0.5III)-Fe-V)(PO4)(2) (A=Sr, Pb) compounds have a distorted yavapaiite structure with space group C2/c, Z = 4 and a = 16.5215(2) angstrom; b = 5.1891(1) angstrom a = 8.0489(1) angstrom; beta = 115.70(1)degrees for [Sr]; a = 16.6925(2) angstrom; b = 5.1832(1) angstrom c = 8.1215(1) angstrom; beta = 115.03(1)degrees for [Pb]. Raman and Infrared spectroscopic study was used to obtain further structural information about the nature of bonding in selected compositions. (C) 2016 Elsevier Masson SAS. All rights reserved.

引用

页码：44 / 54

页数：11

共 40 条

[1] Crystallochemistry and structural studies of two newly CaSb0.50Fe1.50(PO4)3 and Ca0.50SbFe(PO4)3 Nasicon phases [J].