Structure, infrared and Raman spectroscopic studies of newly synthetic AII(SbV0.50FeIII0.50)(PO4)2 (A = Ba, Sr, Pb) phosphates with yavapaiite structure

被引:8
作者
Aatiq, Abderrahim [1 ]
Tigha, My Rachid [1 ]
Fakhreddine, Rachid [1 ]
Bregiroux, Damien [2 ]
Wallez, Gilles [3 ,4 ]
机构
[1] Univ HassanII Casablanca, Fac Sci Ben MSik, Dept Chim, Lab Physicochim Mat Appl, Ave Idriss El Harti,BP 7955, Casablanca, Morocco
[2] Univ Paris 06, Sorbonne Univ, CNRS, Coll France,Lab Chim Matiere Condensee Paris, 11 Pl Marcelin Berthelot, F-75005 Paris, France
[3] CNRS, Chim Paris Tech, Paris Sci & Lettres PSL UMR8247, IRCP, 11 Rue Pierre & Marie Curie, F-75005 Paris, France
[4] Univ Paris 06, Sorbonne Univ, F-75252 Paris 05, France
关键词
Antimony and iron phosphate; Yavapaiite structure; Raman and IR spectroscopy; Rietveld analysis; CRYSTAL-STRUCTURE; ZIRCONIUM DIORTHOPHOSPHATE; PHASE-TRANSITIONS; THERMAL-EXPANSION; NASICON PHASES; CAZR(PO4)(2); CHEMISTRY; CHERALITE; BARIUM; SBOPO4;
D O I
10.1016/j.solidstatesciences.2016.05.009
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The synthesis and structural study of three new A(II)((Sb0.5Fe0.5III)-Fe-V)(PO4)(2) (A=Ba, Sr, Pb) phosphates belonging to the A-Sb-Fe-P-O system were reported here for the first time. Structures of [Ba], [Sr] and [Pb] compounds, obtained by solid state reaction in air atmosphere, were determined at room temperature from X-ray powder diffraction using the Rietveld method. Ba-II(Sb(V)0.5Fe(III)0.5)(PO4)(2) features the yavapaiite-type structure, with space group C2/m, Z = 2 and a = 8.1568(4) angstrom; b = 5.1996(3) angstrom c = 7.8290(4) angstrom; beta = 94.53(1)degrees. A(II)((Sb0.5Fe0.5III)-Fe-V)(PO4)(2) (A=Sr, Pb) compounds have a distorted yavapaiite structure with space group C2/c, Z = 4 and a = 16.5215(2) angstrom; b = 5.1891(1) angstrom a = 8.0489(1) angstrom; beta = 115.70(1)degrees for [Sr]; a = 16.6925(2) angstrom; b = 5.1832(1) angstrom c = 8.1215(1) angstrom; beta = 115.03(1)degrees for [Pb]. Raman and Infrared spectroscopic study was used to obtain further structural information about the nature of bonding in selected compositions. (C) 2016 Elsevier Masson SAS. All rights reserved.
引用
收藏
页码:44 / 54
页数:11
相关论文
共 40 条
[1]   Crystallochemistry and structural studies of two newly CaSb0.50Fe1.50(PO4)3 and Ca0.50SbFe(PO4)3 Nasicon phases [J].
Aatiq, A ;
Tigha, MR ;
Hassine, R ;
Saadoune, I .
POWDER DIFFRACTION, 2006, 21 (01) :45-51
[2]   Structures of two newly synthesized A0.50SbFe(PO4)3 (A=Mn, Cd) Nasicon phases [J].
Aatiq, A ;
Hassine, R ;
Tigha, MR ;
Saadoune, I .
POWDER DIFFRACTION, 2005, 20 (01) :33-39
[3]  
Aatiq A., 2015, J. Mater. Environ. Sci., V6, P3483
[4]   Structure of a new Ca1/3IISb1/6VBi1/2IIIPO4 phosphate [J].
Aatiq, Abderrahim ;
Tigha, My Rachid .
POWDER DIFFRACTION, 2014, 29 (01) :14-19
[5]   Structure, infrared and Raman spectroscopic studies of new Sr0.50SbFe(PO4)3 and SrSb0.50Fe1.50(PO4)3 Nasicon phases [J].
Aatiq, Abderrahim ;
Tigha, My Rachid ;
Benmokhtar, Said .
JOURNAL OF MATERIALS SCIENCE, 2012, 47 (03) :1354-1364
[6]   REDETERMINATION OF THE BETA-CA2P2O7 STRUCTURE [J].
BOUDIN, S ;
GRANDIN, A ;
BOREL, MM ;
LECLAIRE, A ;
RAVEAU, B .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1993, 49 :2062-2064
[7]   Powder pattern indexing with the dichotomy method [J].
Boultif, A ;
Louër, D .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2004, 37 :724-731
[8]   Crystal structure and thermal expansion of the low- and high-temperature forms of BaMIV(PO4)2 compounds (M = Ti, Zr, Hf and Sn) [J].
Bregiroux, D. ;
Popa, K. ;
Jardin, R. ;
Raison, P. E. ;
Wallez, G. ;
Quarton, M. ;
Brunelli, M. ;
Ferrero, C. ;
Caciuffo, R. .
JOURNAL OF SOLID STATE CHEMISTRY, 2009, 182 (05) :1115-1120
[9]   Crystal chemistry of MIIM′IV(PO4)2 double monophosphates [J].
Bregiroux, Damien ;
Popa, Karin ;
Wallez, Gilles .
JOURNAL OF SOLID STATE CHEMISTRY, 2015, 230 :26-33
[10]   Structural study of polymorphism and thermal behavior of CaZr(PO4)2 [J].
Bregiroux, Damien ;
Wallez, Gilles ;
Popa, Karin .
SOLID STATE SCIENCES, 2015, 41 :43-47