7Li and 31P nuclear magnetic resonance studies of Li1-3xMgFexPO4

被引:16
|
作者
Goni, A [1 ]
Bonagamba, TJ
Silva, MA
Panepucci, H
Rojo, T
Barberis, GE
机构
[1] Univ Basque Country, Fac Ciencias, Dept Quim Inorgan, E-48080 Bilbao, Spain
[2] Univ Sao Paulo, Inst Fis Sao Carlos, Dept Fis & Informat, Sao Carlos, SP, Brazil
[3] Univ Estadual Campinas, Inst Fis Gleb Wataghin, BR-13083970 Campinas, SP, Brazil
关键词
D O I
10.1063/1.368043
中图分类号
O59 [应用物理学];
学科分类号
摘要
We report a Li-7 and P-31 nuclear magnetic resonance (NMR) study in the Li1-3xMgFexPO4 phases between 150 and 410 K. This study, complementary to those made using Mossbauer and magnetic neutron diffraction experiments, confirms that the Fe ions enter as Fe(III) in the lattice, and that they enter substituting Li ions. Ionic conductivity measurements, together with the NMR behavior of the Li-7 and P-31 NMR spectra show that no Li mobility occurs in the temperature range studied even with the addition of the Fe impurity. (C) 1998 American Institute of Physics.
引用
收藏
页码:416 / 421
页数:6
相关论文
共 50 条
  • [21] Dynamical Origin of Ionic Conductivity for Li7P3S11 Metastable Crystal As Studied by 6/7Li and 31P Solid-State NMR
    Murakami, Miwa
    Shimoda, Keiji
    Shiotani, Shinya
    Mitsui, Akio
    Ohara, Koji
    Onodera, Yohei
    Arai, Hajime
    Uchimoto, Yoshiharu
    Ogumi, Zempachi
    JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 119 (43): : 24248 - 24254
  • [22] Identification of Li+ binding sites and the effect of Li+ treatment on phospholipid composition in human neuroblastoma cells:: A 7Li and 31P NMR study
    Layden, BT
    Abukhdeir, AM
    Malarkey, C
    Oriti, LA
    Salah, W
    Stigler, C
    Geraldes, CFGC
    de Freitas, DM
    BIOCHIMICA ET BIOPHYSICA ACTA-MOLECULAR BASIS OF DISEASE, 2005, 1741 (03): : 339 - 349
  • [23] 1H AND 7LI MAGNETIC RESONANCE SPECTRA OF SOME ARYLLITHIUMS
    PARKER, J
    LADD, JA
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1969, 19 (01) : 1 - &
  • [24] Comparison of fluorescence, 31P NMR, and 7Li NMR spectroscopic methods for investigating Li+/Mg2+ competition for biomolecules
    Amari, L
    Layden, B
    Rong, QF
    Geraldes, CFGC
    de Freitas, DM
    ANALYTICAL BIOCHEMISTRY, 1999, 272 (01) : 1 - 7
  • [25] Comparison of fluorescence, 31P NMR, and 7Li NMR spectroscopic methods for investigating Li+/Mg2+ competition for biomolecules
    Department of Chemistry, Loyola University Chicago, 6525 North Sheridan Road, Chicago, IL 60626, United States
    不详
    Anal. Biochem., 1 (1-7):
  • [26] Nuclear structure studies with the 7Li(e, elp) reaction
    Lapikás, L
    Wesseling, J
    Wiringa, RB
    PHYSICAL REVIEW LETTERS, 1999, 82 (22) : 4404 - 4407
  • [27] 7Li nuclear magnetic resonance study of lithium insertion in pristine and partially oxidized graphite
    Wang, Y
    Yufit, V
    Guo, X
    Peled, E
    Greenbaum, S
    JOURNAL OF POWER SOURCES, 2001, 94 (02) : 230 - 237
  • [28] A 7LI NUCLEAR MAGNETIC RESONANCE STUDY OF SOLUTIONS OF LITHIUM AND AMMONIUM IONS WITH NITRILOTRIACETIC ACID
    AKITT, JW
    PAREKH, M
    JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (09): : 2195 - &
  • [29] 7Li nuclear magnetic resonance studies of dynamics in a ternary gel polymer electrolyte based on polymeric ionic liquids
    Gouverneur, Martin
    Jeremias, Sebastian
    Schoenhoff, Monika
    ELECTROCHIMICA ACTA, 2015, 175 : 35 - 41
  • [30] Effect of precursors on lithium containing silicate gels studied by 7Li nuclear magnetic resonance
    Szu, S.-P.
    Klein, L.C.
    Greenblatt, M.
    Journal of Non-Crystalline Solids, 1990, 121 (1-3): : 90 - 97