High-quality rGO/MoS2 composite via a facile "prereduction-microwave" strategy for enhanced lithium and sodium storage

被引:27
作者
Liu, Kangli [1 ,2 ,3 ]
Zhang, Peng [1 ,2 ,3 ]
Miao, Fujun [1 ,2 ,3 ]
Zhang, Shijie [1 ,2 ,3 ]
Zhang, Yongshang [1 ,2 ,3 ]
Cao, Guoqin [1 ,2 ,3 ]
Shao, Guosheng [1 ,2 ,3 ]
机构
[1] Zhengzhou Univ, Sch Mat Sci & Engn, Zhengzhou 45001, Peoples R China
[2] Zhengzhou Univ, State Ctr Int Cooperat Designer Low Carbon & Envi, 100 Kexue Ave, Zhengzhou 450001, Peoples R China
[3] Zhengzhou Mat Genome Inst, Bldg 2, Xingyang 40100, Peoples R China
基金
中国国家自然科学基金;
关键词
Prereduction-microwave; rGO/MoS2; Lithium ion batteries; Sodium ion batteries; MOS2; NANOSHEETS; GRAPHENE NANOSHEETS; ANODE MATERIALS; ION; PERFORMANCE; NANOPARTICLES; HYBRID; FOAM; MECHANISM; CAPACITY;
D O I
10.1016/j.jallcom.2019.153207
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
High-quality graphene and graphene-based composites with optimized conductivity and surface chemistry state are crucial to the practical application in electrochemical energy storage and conversion systems. Here, we first propose a facile and general "prereduction-microwave" strategy to repair the lattice defects of reduced graphene oxides composites just in a few seconds, particularly, which has been successfully carried out on rGO/MoS2 composite previously synthesized through the hydrothermal method. This post repaired strategy not only can effectively improve the conductivity of graphene framework, but also well preserve the structural properties of graphene-based composites. Therefore, the optimized rGO/MoS2 composite achieves improved conductivity, good wettability, short ion diffusion length and excellent structural stability compared to the untreated rGO/MoS2 composite, which presents desirable capacity of 734 mAh g(-1) for 200 cycles at 0.5 A g(-1) and 335 mAh g(-1) for 100 cycles at 1 A g(-1) for lithium ion and sodium ion storage, respectively. This method will further promote the development of graphene-based materials for efficient energy storage and conversion. (C) 2019 Elsevier B.V. All rights reserved.
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页数:8
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