An Iron(II) Carbonyl Thiolato Complex Bearing 2-Methoxy-Pyridine: A Structural Model of the Active Site of [Fe] Hydrogenase

被引：20
作者：
Tanino, Soichiro [1 ,2 ]
Ohki, Yasuhiro [1 ,2 ]
Tatsumi, Kazuyuki [1 ,2 ]
机构：
[1] Nagoya Univ, Grad Sch Sci, Chikusa Ku, Dept Chem, Nagoya, Aichi 4648602, Japan
[2] Nagoya Univ, Res Ctr Mat Sci, Chikusa Ku, Nagoya, Aichi 4648602, Japan
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2010年 / 5卷 / 09期
关键词：
carbonyl; hydrogenase; iron; pyridine; thiolate; NIFE HYDROGENASE; CRYSTAL-STRUCTURE; 2,6-DIMESITYLPHENYL THIOLATE; H-2; ACTIVATION; HMD; CLUSTER; SULFUR; DIHYDROGEN; LIGAND; INTERCONVERSION;
D O I：
10.1002/asia.201000408
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Model complex: An Fe∥ complex bearing a thiolate, 2-methoxy-pyridine, and three facially arranged CO ligands was synthesized as a structural analogue of the active site of a CO-inhibited form of [Fe] hydrogenase, from the reaction of [FeBr2(CO)4] with NaS{2, 6-(mesityl)2C 6H3} and the successive treatment with 2-methoxy-pyridine. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：1962 / 1964
页数：3
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