Synthesis and Crystal Structure of Cu(II)/Zn(II)/Mn(II) Complexes Containing 3-((5-(Pyridin-3-yl)-1,3,4-oxadiazol-2-yl)thio)pentane-2,4-dione Ligand

被引：1

作者：

Zhang Qi-Long ^{[1
,2
]}

Sun Le-Tao ^{[2
]}

Yang Xian-Jiong ^{[2
]}

Xu Hong ^{[2
]}

Li Li-Lang ^{[1
]}

Yang Xiao-Sheng ^{[1
]}

机构：

[1] Guizhou Med Univ, State Key Lab Funct & Applicat Med Plants, Guiyang 550014, Peoples R China

[2] Guizhou Med Univ, Sch Basic Med Sci, Guiyang 550025, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2021年 / 37卷 / 06期

关键词：

beta-diketone; Cu(II) coordination polymer; Zn(II) coordination polymer; Mn(II) coordination polymer; crystal structure; METAL-ORGANIC FRAMEWORKS; COORDINATION;

D O I：

10.11862/CJIC.2021.134

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three complexes {[Cu-2(L)(4)]center dot CHCl3}(n) (1), {[Zn(L)(2)]center dot 4CHCl(3)}(n) (2) and ([Mn(L)(2)]center dot 4CHCl(3)}(n) (3) were synthesized from the reaction of 3-((5-(pyridin-3-yl)-1,3,4-oxadiazol-2-yl)thio)pentane-2,4-dione (HL) with Cu(OAc)(2)center dot H2O, Zn(OAc)(2)center dot 2H(2)O and Mn(OAc)(2)center dot 4H(2)O, and characterized by elemental analysis, infrared spectroscopy, powder X-ray diffraction and single-crystal X-ray diffraction. In t h e solid slate, coordination polymer 1 forms ID helical chain structure, and coordination polymer 2 and 3 firm 2D network structure.

引用

页码：989 / 994

页数：6

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