A Facile Route to Cesium Lead Bromoiodide Perovskite Microcrystals and Their Potential Application as Sensors for Nitrophenol Explosives

被引：33

作者：

Aamir, Muhammad ^{[1
,2
]}

Khan, Malik Dilshad ^{[1
]}

Sher, Muhammad ^{[2
]}

Bhosale, Sheshanath V. ^{[3
]}

Malik, Mohammad Azad ^{[1
,4
]}

Akhtar, Javeed ^{[5
]}

Revaprasadu, Neerish ^{[1
]}

机构：

[1] Univ Zululand, Dept Chem, Private Bag X1001, ZA-3886 Kwa Dlangezwa, South Africa

[2] Allama Iqbal Open Univ, Dept Chem, Islamabad, Pakistan

[3] RMIT Univ, Sch Sci, GPO Box 2476, Melbourne, Vic 3001, Australia

[4] Univ Manchester, Sch Mat, Oxford Rd, Manchester M13 9PL, Lancs, England

[5] COMSATS, Inst Informat Technol CIIT, Dept Phys, Polymers & Mat Synth PMS Lab, Islamabad, Pakistan

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2017年 / 31期

基金：

新加坡国家研究基金会;

关键词：

Perovskites; Antisolvents; Crystal growth; Sensors; LIGHT-EMITTING-DIODES; SELECTIVE DETECTION; HALIDE PEROVSKITES; SINGLE-CRYSTALS; SOLAR-CELLS; NANOCRYSTALS; CSPBBR3; PHASE; 2,4,6-TRINITROPHENOL; NANOPARTICLES;

D O I：

10.1002/ejic.201700660

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

To achieve a material with pure phase and crystallinity, the use of antisolvents is found to be crucial. Herein, we report the synthesis of phase-pure CsPbBr2I microcrystals with defined morphologies by using trioctylphosphine (TOP) as an antisolvent and capping agent. The as-prepared inorganic perovskite has enhanced thermal stability and promising optical properties, displaying a band gap of 2.2 eV. The photoluminescence (PL) studies suggest high sensitivity of the as-prepared inorganic perovskites against nitrophenols, which makes them a potential candidate for the detection of nitrophenol.

引用

页码：3755 / 3760

页数：6

共 44 条

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