Tuning of Selectivity for Sustainable Production of Acrolein from Glycerol

被引：14

作者：

Belousov, Artem S. ^{[1
]}

机构：

[1] Lobachevsky State Univ Nizhny Novgorod, Res Inst Chem, Gagarin Ave 23, Nizhnii Novgorod 603022, Russia

来源：

CHEMISTRYSELECT | 2021年 / 6卷 / 34期

关键词：

Acrolein; Biomass; Glycerol; Heterogeneous catalysis; Selectivity control; GAS-PHASE DEHYDRATION; METAL-ORGANIC FRAMEWORKS; BRONSTED ACID SITES; CATALYTIC DEHYDRATION; ACRYLIC-ACID; B-AXIS; ZEOLITE; DEACTIVATION; PHOSPHATE; CONVERSION;

D O I：

10.1002/slct.202102547

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The catalytic dehydration of glycerol into acrolein is a rapidly growing area of both scientific interest and technological importance. The main problem faced by researchers is enhancement of selectivity while maintaining the stability and activity of a catalyst. This minireview is centered on key approaches for tuning of selectivity: changing of physicochemical properties (type of acid sites, its amount, pore and channel size, and doping with noble metals) and selection of optimal reaction conditions (temperature, contact time, feedstock composition, co-feeding O-2 or air). This overview also proposes and discusses the use of metal-organic frameworks as novel catalysts to overcome the main challenges in the dehydration of glycerol.

引用

页码：9191 / 9198

页数：8

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