Self-assembly of high-quality covalently bound organic monolayers onto silicon

被引：101

作者：

Scheres, Luc ^{[1
]}

Arafat, Ahmed ^{[1
]}

Zuilhof, Han ^{[1
]}

机构：

[1] Univ Wageningen & Res Ctr, Organ Chem Lab, NL-6703 HB Wageningen, Netherlands

来源：

LANGMUIR | 2007年 / 23卷 / 16期

关键词：

D O I：

10.1021/la701359k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A very mild method has been developed to obtain covalently attached alkyl monolayers from the attachment of 1-alkynes onto hydrogen-terminated silicon surfaces at room temperature in the dark. Apart from being the mildest method reported so far for the preparation of such monolayers, their quality, as indicated by water contact angles, XPS, and infrared spectroscopy, equals within experimental error that of the best reported alkyl monolayers on silicon.

引用

页码：8343 / 8346

页数：4

共 40 条

[1] New synthetic routes to alkyl monolayers on the Si(111) surface [J].

Boukherroub, R ;

Morin, S ;

Bensebaa, F ;

Wayner, DDM .

LANGMUIR, 1999, 15 (11) :3831-3835

[2] Chemical reactivity of hydrogen-terminated crystalline silicon surfaces [J].

Boukherroub, Rabah .

CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 2005, 9 (1-2) :66-72

[3] External reflection infrared spectroscopy of anisotropic adsorbate layers on dielectric substrates [J].

Brunner, H ;

Mayer, U ;

Hoffmann, H .

APPLIED SPECTROSCOPY, 1997, 51 (02) :209-217

[4] Photoluminescence of porous silicon surfaces stabilized through Lewis acid mediated hydrosilylation [J].

Buriak, JM ;

Allen, MJ .

JOURNAL OF LUMINESCENCE, 1998, 80 (1-4) :29-35

[5] Lewis acid mediated hydrosilylation on porous silicon surfaces [J].

Buriak, JM ;

Stewart, MP ;

Geders, TW ;

Allen, MJ ;

Choi, HC ;

Smith, J ;

Raftery, D ;

Canham, LT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (49) :11491-11502

[6] Organometallic chemistry on silicon and germanium surfaces [J].

Buriak, JM .

CHEMICAL REVIEWS, 2002, 102 (05) :1271-1308

[7] Lewis acid mediated functionalization of porous silicon with substituted alkenes and alkynes [J].

Buriak, JM ;

Allen, MJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (06) :1339-1340

[8] Photoreactivity of unsaturated compounds with hydrogen-terminated silicon(111) [J].

Cicero, RL ;

Linford, MR ;

Chidsey, CED .

LANGMUIR, 2000, 16 (13) :5688-5695

[9] Covalently attached saccharides on silicon surfaces [J].

de Smet, LCPM ;

Stork, GA ;

Hurenkamp, GHF ;

Sun, QY ;

Topal, H ;

Vronen, PJE ;

Sieval, AB ;

Wright, A ;

Visser, GM ;

Zuilhof, H ;

Sudhölter, EJR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (46) :13916-13917

[10] Si-C linked organic monolayers on crystalline silicon surfaces as alternative gate insulators [J].

Faber, EJ ;

de Smet, LCPM ;

Olthuis, W ;

Zuilhof, H ;

Sudhölter, EJR ;

Bergveld, P ;

van den Berg, A .

CHEMPHYSCHEM, 2005, 6 (10) :2153-2166

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