Preparation of nitrogen-doped ZnSe thin films by radical-assisted MOCVD

被引:1
作者
Hara, Y [1 ]
Yonekura, H [1 ]
Noda, Y [1 ]
机构
[1] Tohoku Univ, Fac Engn, Dept Mat Sci, Aoba Ku, Sendai, Miyagi 9808579, Japan
来源
MATERIALS TRANSACTIONS JIM | 1998年 / 39卷 / 03期
关键词
metalorganic chemical vapor deposition; zinc selenide; nitrogen doping; photoluminescence; bound exciton; nitrogen pair; net acceptor concentration;
D O I
10.2320/matertrans1989.39.427
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Radical-assisted metalorganic chemical vapor deposition of ZnSe thin films was made using nitrogen trifluoride (NF3) as co-reactant and source of nitrogen atoms. The secondary ion mass spectroscopy analysis indicated that the concentration profile of nitrogen in a ZnSe film was not uniform in regard to the thickness and was the order of magnitude of 10(25)-10(26) m(-3). The photoluminescence (PL) spectra of all the films showed weak excitonic emission bound due to the neutral nitrogen atom pair (I-1(N-N)) and intense donor-acceptor pair emission (DAP). The net acceptor concentration obtained from capacitance-voltage measurements was 1.3 x 10(23) m(-3) at maximum, which increased to 1.3 x 10(24) m(-3) after heat-treatment.
引用
收藏
页码:427 / 431
页数:5
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