Reaction of single-walled carbon nanotubes with organic peroxides

被引：36

作者：

Engel, Paul S. ^{[1
]}

Billups, Wilbur E. ^{[1
]}

Abmayr, David W., Jr. ^{[1
]}

Tsvaygboym, Konstantin ^{[1
]}

Wang, Runtang ^{[1
]}

机构：

[1] Rice Univ, Dept Chem, Houston, TX 77251 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2008年 / 112卷 / 03期

关键词：

D O I：

10.1021/jp0770054

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Single-walled carbon nanotubes (SWNTs) induce the decomposition of four diacyl peroxides by single electron transfer (SET). Phthaloyl peroxide functionalizes SWNTs to the greatest extent of the four. It was also found that t-butoxy radicals add to SWNTs but that SWNTs fail to inhibit cumene autoxidation. Thus, SWNTs are reactive to alkoxy radicals but not to alkylperoxy radicals.

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页码：695 / 700

页数：6

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