Strong ferromagnetic metal-ligand exchange in a nickel bis(3,5-dipyridylverdazyl)complex

被引：41

作者：

Brook, David J. R. ^{[1
]}

Richardson, Cardius J. ^{[1
]}

Haller, Benjamin C. ^{[1
]}

Hundley, Michael ^{[2
]}

Yee, Gordon T. ^{[2
]}

机构：

[1] San Jose State Univ, Dept Chem, San Jose, CA 95192 USA

[2] Virginia Polytech Inst & State Univ, Dept Chem, Blacksburg, VA 24061 USA

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 35期

关键词：

COORDINATED VERDAZYL RADICALS; MAGNETIC-PROPERTIES; SPECTROSCOPIC PROPERTIES; PROTONIC MODULATION; COMPLEXES; NITROXIDE; DERIVATIVES; COBALT(II); CHEMISTRY; IONS;

D O I：

10.1039/c0cc02233k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new 1,5-dipyridyl verdazyl, synthesized from the corresponding dipyridyl hydrazone, coordinates nickel(II) to form a structurally characterized, pseudooctahedral complex analogous to Ni(terpy)(2)(2+). The unusually short Ni-verdazyl distance results in strong ferromagnetic exchange (J(Ni-rad) = + 300, J(rad-rad) = + 160 cm(-1)) between all three paramagnetic species along with a metal-ligand charge transfer band in the electronic spectrum.

引用

页码：6590 / 6592

页数：3

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