Luminescence from lanthanide(3+) ions in solution

被引：163
作者：
Dossing, A [1 ]
机构：
[1] Univ Copenhagen, Dept Chem, DK-2100 Copenhagen, Denmark
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2005年 / 08期
关键词：
lanthanides; luminescence; fluorescent probes;
D O I：
10.1002/ejic.200401043
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
An over-view of recent work dealing with luminescence properties in solution of complexes of the lanthanide(3+) ions Nd3+, EU3+, Tb3+, Er3+ and Yb3+ in which an organic chromophore is attached to the metal centre as a sensitizer is given. The various factors that influence the metal-centred luminescence lifetime and intensity are discussed and illustrated with own results and recent literature examples. The VIS emitting metal ions Eu3+ and Tb3+ require sensitizers that absorb light in the UV or near UV range whereas VIS absorbing sensitizers can be used for the NIR emitting ions Nd3+, Er3+ and Yb3+. The latter type of complexes is currently of great interest because of potential applications as luminescent markers in biological systems. (c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005).
引用
收藏
页码：1425 / 1434
页数：10
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