Luminescence from lanthanide(3+) ions in solution

被引：167

作者：

Dossing, A ^{[1
]}

机构：

[1] Univ Copenhagen, Dept Chem, DK-2100 Copenhagen, Denmark

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2005年 / 08期

关键词：

lanthanides; luminescence; fluorescent probes;

D O I：

10.1002/ejic.200401043

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An over-view of recent work dealing with luminescence properties in solution of complexes of the lanthanide(3+) ions Nd3+, EU3+, Tb3+, Er3+ and Yb3+ in which an organic chromophore is attached to the metal centre as a sensitizer is given. The various factors that influence the metal-centred luminescence lifetime and intensity are discussed and illustrated with own results and recent literature examples. The VIS emitting metal ions Eu3+ and Tb3+ require sensitizers that absorb light in the UV or near UV range whereas VIS absorbing sensitizers can be used for the NIR emitting ions Nd3+, Er3+ and Yb3+. The latter type of complexes is currently of great interest because of potential applications as luminescent markers in biological systems. (c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005).

引用

页码：1425 / 1434

页数：10

共 51 条

[1] ANTENNA EFFECT IN LUMINESCENT LANTHANIDE CRYPTATES - A PHOTOPHYSICAL STUDY [J].

ALPHA, B ;

BALLARDINI, R ;

BALZANI, V ;

LEHN, JM ;

PERATHONER, S ;

SABBATINI, N .

PHOTOCHEMISTRY AND PHOTOBIOLOGY, 1990, 52 (02) :299-306

[2] Non-radiative deactivation of the excited states of europium, terbium and ytterbium complexes by proximate energy-matched OH, NH and CH oscillators: an improved luminescence method for establishing solution hydration states [J].

Beeby, A ;

Clarkson, IM ;

Dickins, RS ;

Faulkner, S ;

Parker, D ;

Royle, L ;

de Sousa, AS ;

Williams, JAG ;

Woods, M .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1999, (03) :493-503

[3] CRYSTAL-STRUCTURES OF THE LANTHANUM(III), EUROPIUM(III), AND TERBIUM(III) CRYPTATES OF TRIS(BIPYRIDINE) MACROBICYCLIC LIGANDS [J].

BKOUCHEWAKSMAN, I ;

GUILHEM, J ;

PASCARD, C ;

ALPHA, B ;

DESCHENAUX, R ;

LEHN, JM .

HELVETICA CHIMICA ACTA, 1991, 74 (06) :1163-1170

[4] THERMODYNAMIC STUDY OF LANTHANIDE COMPLEXES OF 1,4,7-TRIAZACYCLONONANE-N,N',N''-TRIACETIC ACID AND 1,4,7,10-TETRAAZACYCLODODECANE-N,N',N'',N'''-TETRAACETIC ACID [J].

CACHERIS, WP ;

NICKLE, SK ;

SHERRY, AD .

INORGANIC CHEMISTRY, 1987, 26 (06) :958-960

[5] ELECTRONIC ENERGY LEVELS IN TRIVALENT LANTHANIDE AQUO IONS .I. PR3+ ND3+ PM3+ SM3+ DY3+ HO3+ ER3+ AND TM3+ [J].

CARNALL, WT ;

FIELDS, PR ;

RAJNAK, K .

JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (10) :4424-&

[6] ELECTRONIC ENERGY LEVELS OF TRIVALENT LANTHANIDE AQUO IONS .4. EU3+ [J].

CARNALL, WT ;

FIELDS, PR ;

RAJNAK, K .

JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (10) :4450-&

[7]

CARNALL WT, 1968, J CHEM PHYS, V49, P4447, DOI 10.1063/1.1669895

[8] Spectroscopic properties and design of highly luminescent lanthanide coordination complexes [J].

de Sá, GF ;

Malta, OL ;

Donegá, CD ;

Simas, AM ;

Longo, RL ;

Santa-Cruz, PA ;

da Silva, EF .

COORDINATION CHEMISTRY REVIEWS, 2000, 196 :165-195

[9] A THEORY OF SENSITIZED LUMINESCENCE IN SOLIDS [J].

DEXTER, DL .

JOURNAL OF CHEMICAL PHYSICS, 1953, 21 (05) :836-850

[10] NILE RED AS A SOLVATOCHROMIC DYE FOR MEASURING SOLVENT STRENGTH IN NORMAL LIQUIDS AND MIXTURES OF NORMAL LIQUIDS WITH SUPERCRITICAL AND NEAR CRITICAL FLUIDS [J].

DEYE, JF ;

BERGER, TA ;

ANDERSON, AG .

ANALYTICAL CHEMISTRY, 1990, 62 (06) :615-622

← 1 2 3 4 5 6 →