A Perylenediimide Tetramer-Based 3D Electron Transport Material for Efficient Planar Perovskite Solar Cell

被引：30

作者：

Cheng, Ming ^{[1
]}

Li, Yuanyuan ^{[2
]}

Liu, Peng ^{[3
]}

Zhang, Fuguo ^{[1
,3
]}

Hajian, Alireza ^{[2
,3
]}

Wang, Haoxin ^{[4
]}

Li, Jiajia ^{[4
]}

Wang, Linqin ^{[1
]}

Kloo, Lars ^{[3
]}

Yang, Xichuan ^{[4
]}

Sun, Licheng ^{[1
,4
]}

机构：

[1] KTH Royal Inst Technol, Dept Chem, Organ Chem, SE-10044 Stockholm, Sweden

[2] KTH Royal Inst Technol, Dept Fibre Polymer Technol Chem Sci, Wallenberg Wood Sci Ctr, Engn, SE-10044 Stockholm, Sweden

[3] KTH Royal Inst Technol, Dept Chem, Appl Phys Chem, SE-10044 Stockholm, Sweden

[4] DUT, DUT KTH Joint Educ & Res Ctr Mol Devices, Inst Artificial Photosynth, State Key Lab Fine Chem, Dalian 116024, Peoples R China

来源：

SOLAR RRL | 2017年 / 1卷 / 05期

基金：

瑞典研究理事会; 中国国家自然科学基金;

关键词：

HALIDE PEROVSKITES; ACCEPTOR; PERFORMANCE; DERIVATIVES; VOLTAGE; LENGTHS;

D O I：

10.1002/solr.201700046

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

A perylenediimide (PDI) tetramer-based three dimensional (3D) molecular material, termed SFX-PDI4, has been designed, synthesized, and characterized. The low-lying HOMO and LUMO energy levels, high electron mobility and good film-formation property make it a promising electron transport material (ETM) in inverted planar perovskite solar cells (PSCs). The device exhibits a high power conversion efficiency (PCE) of 15.3% with negligible hysteresis, which can rival that of device based on PC61BM. These results demonstrate that three dimensional PDI-based molecular materials could serve as high performance ETMs in PSCs.

引用

页数：7

共 41 条

[1] Highly efficient planar perovskite solar cells through band alignment engineering [J].

Baena, Juan Pablo Correa ;

Steier, Ludmilla ;

Tress, Wolfgang ;

Saliba, Michael ;

Neutzner, Stefanie ;

Matsui, Taisuke ;

Giordano, Fabrizio ;

Jacobsson, T. Jesper ;

Kandada, Ajay Ram Srimath ;

Zakeeruddin, Shaik M. ;

Petrozza, Annamaria ;

Abate, Antonio ;

Nazeeruddin, Mohammad Khaja ;

Graetzel, Michael ;

Hagfeldt, Anders .

ENERGY & ENVIRONMENTAL SCIENCE, 2015, 8 (10) :2928-2934

[2] Reduced voltage losses yield 10% efficient fullerene free organic solar cells with >1 V open circuit voltages [J].

Baran, D. ;

Kirchartz, T. ;

Wheeler, S. ;

Dimitrov, S. ;

Abdelsamie, M. ;

Gorman, J. ;

Ashraf, R. S. ;

Holliday, S. ;

Wadsworth, A. ;

Gasparini, N. ;

Kaienburg, P. ;

Yan, H. ;

Amassian, A. ;

Brabec, C. J. ;

Durrant, J. R. ;

McCulloch, I. .

ENERGY & ENVIRONMENTAL SCIENCE, 2016, 9 (12) :3783-3793

[3]

Bi DQ, 2016, NAT ENERGY, V1, DOI [10.1038/nenergy.2016.142, 10.1038/NENERGY.2016.142]

[4] Facile synthesized organic hole transporting material for perovskite solar cell with efficiency of 19.8% [J].

Bi, Dongqin ;

Xu, Bo ;

Gao, Peng ;

Sun, Licheng ;

Graetzel, Michael ;

Hagfeldt, Anders .

NANO ENERGY, 2016, 23 :138-144

[5] Electrochemical Considerations for Determining Absolute Frontier Orbital Energy Levels of Conjugated Polymers for Solar Cell Applications [J].

Cardona, Claudia M. ;

Li, Wei ;

Kaifer, Angel E. ;

Stockdale, David ;

Bazan, Guillermo C. .

ADVANCED MATERIALS, 2011, 23 (20) :2367-2371

[6] Application of benzodithiophene based A-D-A structured materials in efficient perovskite solar cells and organic solar cells [J].

Chen, Cheng ;

Cheng, Ming ;

Liu, Peng ;

Gao, Jiajia ;

Kloo, Lars ;

Sun, Licheng .

NANO ENERGY, 2016, 23 :40-49

[7] Efficient and stable large-area perovskite solar cells with inorganic charge extraction layers [J].

Chen, Wei ;

Wu, Yongzhen ;

Yue, Youfeng ;

Liu, Jian ;

Zhang, Wenjun ;

Yang, Xudong ;

Chen, Han ;

Bi, Enbing ;

Ashraful, Islam ;

Graetzel, Michael ;

Han, Liyuan .

SCIENCE, 2015, 350 (6263) :944-948

[8] Acceptor Donor Acceptor type ionic molecule materials for efficient perovskite solar cells and organic solar cells [J].

Cheng, Ming ;

Aitola, Kerttu ;

Chen, Cheng ;

Zhang, Fuguo ;

Liu, Peng ;

Sveinbjornsson, Kari ;

Hua, Yong ;

Kloo, Lars ;

Boschloo, Gerrit ;

Sun, Licheng .

NANO ENERGY, 2016, 30 :387-397

[9] Phenoxazine-Based Small Molecule Material for Efficient Perovskite Solar Cells and Bulk Heterojunction Organic Solar Cells [J].

Cheng, Ming ;

Xu, Bo ;

Chen, Cheng ;

Yang, Xichuan ;

Zhang, Fuguo ;

Tan, Qin ;

Hua, Yong ;

Kloo, Lars ;

Sun, Licheng .

ADVANCED ENERGY MATERIALS, 2015, 5 (08)

[10] Synthesis of spiro[fluorene-9,9′-xanthene] derivatives and their application as hole-transporting materials for organic light-emitting devices [J].

Chu, Zengze ;

Wang, Dan ;

Zhang, Chao ;

Wang, Fuzhi ;

Wu, Hongwei ;

Lv, Zhibin ;

Hou, Shaocong ;

Fan, Xing ;

Zou, Dechun .

SYNTHETIC METALS, 2012, 162 (7-8) :614-620

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