RHIZOPHORA APICULATA AS ECO-FRIENDLY INHIBITOR AGAINST MILD STEEL CORROSION IN 1M HCL

被引:19
作者
Asaad, Mohammad Ali [1 ]
Ismail, Mohammad [1 ]
Raja, Pandian Bothi [2 ]
Khalid, Nur Hafizah A. [1 ]
机构
[1] Univ Teknol Malaysia, Dept Civil Engn, Utm Johor Bahru 81310, Johor, Malaysia
[2] Univ Teknol Petronas, Ctr Corros Res, Tronoh 32610, Perak, Malaysia
关键词
Rhizophora apiculata; mild steel; corrosion inhibition; plant extract; weight loss; adsorption; HYDROCHLORIC-ACID; MANGROVE TANNIN; EXTRACT; COPPER; MEDIA;
D O I
10.1142/S0218625X18500130
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The inhibitive characteristics of aqueous extracts from mangrove (Rhizophora apiculata) bark and leaf on the corrosion of mild steel (MS) coupon in 1M HCl were examined by means of the gravimetric measurement (weight loss), electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization techniques. The MS surface morphologie were investigated using field emission scanning electron microscopy (FESEM) with Energy Dispersive X-Ray Analysis (EDX) at 120 h in the presence and absence of green inhibitors in corrosive medium. Respective inhibition efficiencies of 68.1% and 59.0% were obtained when exposed to 10% v/v Rhizophora apiculata solution for 72 h. Examination of the adsorption behavior of the solutions indicated the Langmuir isotherm model as being the most likely relevant adsorption mechanism. In addition, polarization measurements showed that both bark and leaves extract inhibitors act via mixed type inhibition.
引用
收藏
页数:11
相关论文
共 39 条
[1]  
Abdulrahman A., 2011, INT REV MECH ENG, V5, P59
[2]   Cocos nucifera L. water as green corrosion inhibitor for acid corrosion of aluminium in HCl solution [J].
Abiola, Olusegun K. ;
Tobun, Y. .
CHINESE CHEMICAL LETTERS, 2010, 21 (12) :1449-1452
[3]  
Al-Mhyawi S. R., 2014, AFR J PURE APPL CHEM, V8, P14
[4]   Corrosion inhibition and adsorption mechanism studies of Hunteria umbellata seed husk extracts on mild steel immersed in acidic solutions [J].
Alaneme, Kenneth Kanayo ;
Olusegun, Sunday Joseph ;
Adelowo, Oluwabunkunmi Tomi .
ALEXANDRIA ENGINEERING JOURNAL, 2016, 55 (01) :673-681
[5]   Corrosion and corrosion control of mild steel in concentrated H2SO4 solutions by a newly synthesized glycine derivative [J].
Amin, Mohammed A. ;
Ibrahim, Mohamed M. .
CORROSION SCIENCE, 2011, 53 (03) :873-885
[6]   Adsorption and electrochemical studies of Pimenta dioica leaf extracts as corrosion inhibitor for mild steel in hydrochloric acid [J].
Anupama, K. K. ;
Ramya, K. ;
Shainy, K. M. ;
Joseph, Abraham .
MATERIALS CHEMISTRY AND PHYSICS, 2015, 167 :28-41
[7]   Chemically modified natural polysaccharide as green corrosion inhibitor for mild steel in acidic medium [J].
Banerjee, Sitashree ;
Srivastava, Varsha ;
Singh, M. M. .
CORROSION SCIENCE, 2012, 59 :35-41
[8]   Gum Arabic as an eco-friendly inhibitor for API 5L X42 pipeline steel in HCl medium [J].
Bentrah, Hamza ;
Rahali, Youssouf ;
Chala, Abdelouahad .
CORROSION SCIENCE, 2014, 82 :426-431
[9]  
Choudhari A. B., 2011, Journal of Pharmacy Research, V4, P570
[10]  
Dipjyoti K, 2016, INT J PHARM PHYCH RE, V8, P239