Luminescent properties of 4,4-bipyridinium chlorobismuthate salt: Strong influence of solvation

被引：36

作者：

Adonin, Sergey A. ^{[1
,2
]}

Sokolov, Maxim N. ^{[1
,2
]}

Rakhmanova, Marianna E. ^{[1
]}

Smolentsev, Anton I. ^{[1
,2
]}

Korolkov, Ilya V. ^{[1
]}

Kozlova, Svetlana G. ^{[1
,2
]}

Fedin, Vladimir P. ^{[1
,2
]}

机构：

[1] Nikolaev Inst Inorgan Chem SB RAS, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, Novosibirsk 630090, Russia

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2015年 / 54卷

基金：

俄罗斯科学基金会;

关键词：

Chlorobismuthate; Bismuth; Solvate; Luminescence; IODOBISMUTHATES;

D O I：

10.1016/j.inoche.2015.02.020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of BiCl3 and 4,4-bipy in 2 M HCl leads to the formation of 4,4-bipyridinium salt of binuclear chlorobismuthate complex (bipyH(2))(2)[Bi2Cl10]center dot 2H(2)O (1). When heated in air, 1 loses the solvate water molecules to give (bipyH(2))(2)[Bi2Cl10] (2). The dehydration results in significant changes in luminescent behavior. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：89 / 91

页数：3

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