Investigation of the Hydrogen-Rich Reduction of Panzhihua Ilmenite Concentrate Pellets

被引:12
作者
Chen, Furong [1 ]
Lv, Wei [1 ]
Zhou, Gangwei [1 ]
Liu, Zhuoliang [1 ]
Chu, Mansheng [1 ,2 ]
Lv, Xuewei [2 ]
机构
[1] Northeastern Univ, Sch Met, Shenyang 110819, Peoples R China
[2] Chongqing Univ, Coll Mat Sci & Engn, Chongqing 400044, Peoples R China
基金
中国国家自然科学基金;
关键词
Ilmenite concentrate; Pellet; Hydrogen-rich reduction; Hydrogen metallurgy; CARBOTHERMIC REDUCTION; KINETICS; TITANIUM; TITANOMAGNETITE; IRON; PREOXIDATION; MECHANISM; RECOVERY; BEHAVIOR; POWDER;
D O I
10.1007/s40831-022-00555-3
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The hydrogen-rich reduction of ilmenite concentrates has a significant effect on the reduction of the carbon footprint of the titanium slag production process. This study investigates the hydrogen-rich reduction of Panzhihua ilmenite concentrate pellets. The pellets were roasted at 500, 700, 900, and 1100 degrees C and used as the raw material for the reduction process. The effects of the pellet roasting temperature, magnetite concentrate content of the pellets, reduction temperature, and reducing gas composition on the reduction process were experimentally studied. The results showed that the average reduction rate is affected by the phase and dense structure of the pellet, reduction temperature, and hydrogen content. Further, the reduction process can be accelerated by increasing the H-2 content and reduction temperature. The high compressive strength of the pellet, owing to its dense inner structure, is not conducive for the reduction process. Moreover, studies show that the H-2/CO ratio has negligible effects on the reduction mechanism. The reaction mechanism of the pellet reduction process is three-dimensional diffusion. Furthermore, the effect of the pellet phase on the hydrogen-rich reduction process has been discussed. [GRAPHICS] .
引用
收藏
页码:1130 / 1139
页数:10
相关论文
共 34 条
[1]   Evaluation of Low Cost Titanium Alloy Products [J].
Barnes, John E. ;
Peter, William ;
Blue, Craig A. .
LIGHT METALS TECHNOLOGY 2009, 2009, 618-619 :165-+
[2]   A novel process for recovery of iron, titanium, and vanadium from titanomagnetite concentrates: NaOH molten salt roasting and water leaching processes [J].
Chen, Desheng ;
Zhao, Longsheng ;
Liu, Yahui ;
Qi, Tao ;
Wang, Jianchong ;
Wang, Lina .
JOURNAL OF HAZARDOUS MATERIALS, 2013, 244 :588-595
[3]   Simultaneous removal of Cr(III) and V(V) and enhanced synthesis of high-grade rutile TiO2 based on sodium carbonate decomposition [J].
Chen, Guo ;
Jiang, Qi ;
Li, Kangqiang ;
He, Aoxi ;
Peng, Jinhui ;
Omran, Mamdouh ;
Chen, Jin .
JOURNAL OF HAZARDOUS MATERIALS, 2020, 388
[4]   Gaseous Reduction Behavior of Primary Ilmenite at Temperatures Between 1273 K and 1473 K [J].
Choi, Kyungsob ;
Jeon, Ho Seok ;
Lee, Sujeong ;
Kim, Youngjae ;
Park, Hyunsik .
METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE, 2022, 53 (01) :334-341
[5]   Kinetics and mechanism of hydrogen reduction of ilmenite powders [J].
Dang, Jie ;
Zhang, Guo-hua ;
Chou, Kuo-chih .
JOURNAL OF ALLOYS AND COMPOUNDS, 2015, 619 :443-451
[6]   Non-isothermal reduction kinetics of titanomagnetite by hydrogen [J].
Dang, Jie ;
Zhang, Guo-hua ;
Hu, Xiao-jun ;
Chou, Kuo-chih .
INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS, 2013, 20 (12) :1134-1140
[7]   Influence of pressure on the kinetics of synthetic ilmenite reduction in hydrogen [J].
de Vries, ML ;
Grey, IE .
METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE, 2006, 37 (02) :199-208
[8]   Isothermal reduction of powdery 2CaO•Fe2O3 and CaO•Fe2O3 under H2 atmosphere [J].
Ding, Chengyi ;
Lv, Xuewei ;
Li, Gang ;
Bai, Chenguang ;
Xuan, Senwei ;
Tang, Kai ;
Lv, Xueming .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2018, 43 (01) :24-36
[9]   Influence of Pre-oxidation on Carbothermic Reduction Process of Ilmenite Concentrate [J].
Gou, Hai-Peng ;
Zhang, Guo-Hua ;
Chou, Kuo-Chih .
ISIJ INTERNATIONAL, 2015, 55 (05) :928-933
[10]   Balance of raw input and energy of titanium slag smelting in closed high power Direct Current Electric Arc Furnace [J].
Han, Fengxia ;
Sang, Xiuli ;
Xu, Jianxin .
RESOURCES AND SUSTAINABLE DEVELOPMENT, PTS 1-4, 2013, 734-737 :1516-1521