Time-resolved near infrared surface-enhanced Raman scattering spectroscopy of a surface-confined electrochemical reaction

被引：2

作者：

Ishioka, T ^{[1
]}

Uchida, T ^{[1
]}

Teramae, N ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan

来源：

CHEMISTRY LETTERS | 1998年 / 08期

关键词：

D O I：

10.1246/cl.1998.771

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A time-resolved surface-enhanced Raman scattering (SERS) system was developed using a step-scan near-infrared Fourier transform(FT) spectrometer. The developed system with a submillisecond time resolution was applied to a surface-confined reaction of totally two-electron redox of 9,10-phenanthrenequinone(PQ). From the electrochemical and spectroscopic results, the standard electrochemical rate constant was calculated to be 0.08 s(-1) for PQ adsorbed on a Au electrode.

引用

页码：771 / 772

页数：2

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