Immobilized nickel(II) on organic-inorganic hybrid materials: The effective and reusable catalysts for Biginelli reaction

被引：11
|
作者：
Zhang LiYuan [1 ,2 ]
Wang ChuanHu [2 ]
Zhou Li [2 ]
Li PinHua [1 ]
Zhang XiuLi [3 ]
Wang Lei [1 ,4 ]
机构：
[1] Huaibei Normal Univ, Dept Chem, Huaibei 235000, Peoples R China
[2] Bengbu Coll, Expt Chem Ctr, Bengbu 233030, Peoples R China
[3] Anhui Agr Univ, Coll Sci, Hefei 230036, Peoples R China
[4] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
SCIENCE CHINA-CHEMISTRY | 2011年 / 54卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Biginelli reaction; immobilization of nickel(II); organic-inorganic hybrid material; heterogeneous catalyst; ONE-POT SYNTHESIS; CONDENSATION REACTION; COPPER-FREE; EFFICIENT SYNTHESIS; LANTHANUM CHLORIDE; IMPROVED PROTOCOL; HIGHLY EFFICIENT; SILICA-GEL; DIHYDROPYRIMIDINONES; PALLADIUM;
D O I：
10.1007/s11426-010-4178-6
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The immobilized nickel(I I) on the organic-inorganic hybrid material was prepared and used as an effective catalyst for the Biginelli reaction. In the presence of the immobilized nickel catalyst, aromatic aldehydes reacted with ethyl acetoacetate and urea (or thiourea) smoothly to generate the corresponding Biginelli products in good to excellent yields without using any additive. The work-up procedure is very simple and practical. Furthermore, the silica-supported nickel(II) could be recovered and recycled for six consecutive trials without significant loss of its catalytic activity.
引用
收藏
页码：74 / 80
页数：7
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