Solvent-free porous framework resulted from 3D entanglement of 1D zigzag coordination polymer

被引:9
作者
Kole, Goutam Kumar [2 ]
Cairns, Amy J. [1 ]
Eddaoudi, Mohamed [1 ,3 ]
Vittal, Jagadese J. [2 ]
机构
[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA
[2] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
[3] King Abdullah Univ Sci & Technol, KAUST Adv Membranes & Porous Mat Ctr, Chem & Life Sci & Engn Div, Thuwal 239556900, Saudi Arabia
关键词
METAL-ORGANIC FRAMEWORKS; HYDROGEN STORAGE; SORPTION PROPERTIES; GAS-ADSORPTION; NETWORK; EXCHANGE; CRYSTAL; CHAINS; ARCHITECTURES; CHEMISTRY;
D O I
10.1039/c0nj00217h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A solvent-free porous metal organic framework is constructed by the 3D entanglement of 1D zigzag coordination polymeric chains. The role of solvents and the effect of reaction conditions on such unique entanglement are addressed.
引用
收藏
页码:2392 / 2395
页数:4
相关论文
共 54 条
[1]  
Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO
[2]  
2-Z
[3]   Influence of connectivity and porosity on ligand-based luminescence in zinc metal-organic frameworks [J].
Bauer, Christina A. ;
Timofeeva, Tatiana V. ;
Settersten, Thomas B. ;
Patterson, Brian D. ;
Liu, Vincent H. ;
Simmons, Blake A. ;
Allendorf, Mark D. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (22) :7136-7144
[4]   Coordination Polymers Versus Metal-Organic Frameworks [J].
Biradha, Kumar ;
Ramana, Arunachalam ;
Vittal, Jagadese J. .
CRYSTAL GROWTH & DESIGN, 2009, 9 (07) :2969-2970
[5]   Permanent microporosity and enantioselective sorption in a chiral open framework [J].
Bradshaw, D ;
Prior, TJ ;
Cussen, EJ ;
Claridge, JB ;
Rosseinsky, MJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (19) :6106-6114
[6]   Crystal engineering of coordination polymers and architectures using the [Cu(2,2′-bipy)]2+ molecular corner as building block (bipy=2,2′-bipyridyl) [J].
Carlucci, Lucia ;
Ciani, Gianfranco ;
Gramaccioli, Alberto ;
Proserpio, Davide M. ;
Rizzato, Silvia .
CRYSTENGCOMM, 2000, (29) :154-163
[7]   Unprecedented 3D entanglement of 1D zigzag coordination polymers leading to a robust microporous framework [J].
Cheng, Ai-Ling ;
Liu, Na ;
Yue, Yan-Feng ;
Jiang, Yong-Wen ;
Gao, En-Qing ;
Yan, Chun-Hua ;
He, Ming-Yuan .
CHEMICAL COMMUNICATIONS, 2007, (04) :407-409
[8]   Towards tuning the packing and entanglement of zigzag coordination chains by terminal ligands [J].
Cheng, Aii-Ling ;
Ma, Yu ;
Zhang, Jian-Yong ;
Gao, En-Qing .
DALTON TRANSACTIONS, 2008, (15) :1993-2004
[9]   Synthesis, X-ray crystal structures, and gas sorption properties of pillared square grid nets based on paddle-wheel motifs: Implications for hydrogen storage in porous materials [J].
Chun, H ;
Dybtsev, DN ;
Kim, H ;
Kim, K .
CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (12) :3521-3529
[10]   Hydrogen storage in microporous metal-organic frameworks with exposed metal sites [J].
Dinca, Mircea ;
Long, Jeffrey R. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (36) :6766-6779