Finite-temperature critical point of a glass transition

被引:69
作者
Elmatad, Yael S. [1 ]
Jack, Robert L. [2 ]
Chandler, David [1 ]
Garrahan, Juan P. [3 ]
机构
[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[2] Univ Bath, Dept Phys, Bath BA2 7AY, Avon, England
[3] Univ Nottingham, Sch Phys & Astron, Nottingham NG7 2RD, England
基金
美国国家科学基金会;
关键词
critical behavior; supercooled liquids; SUPERCOOLED LIQUIDS; SPACE-TIME; DYNAMICS; SYSTEMS; MODELS; CONNECTIONS; RELAXATION; FORMERS;
D O I
10.1073/pnas.1006306107
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
We generalize the simplest kinetically constrained model of a glass-forming liquid by softening kinetic constraints, allowing them to be violated with a small rate. We demonstrate that this model supports a first-order dynamical (space-time) phase transition between active (fluid) and inactive (glass) phases. The first-order phase boundary in this softened model ends in a finite-temperature dynamical critical point, which may be present in natural systems. In this case, the glass phase has a very large but finite relaxation time. We discuss links between the dynamical critical point and quantum phase transitions, showing that dynamical phase transitions in d dimensions map to quantum transitions in the same dimension, and hence to classical thermodynamic phase transitions in d + 1 dimensions.
引用
收藏
页码:12793 / 12798
页数:6
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