Synthesis and photocatalytic properties of the graphene-La2Ti2O7 nanocomposites

被引:53
作者
Wu, ChunHui [1 ]
Zhang, YongZheng [1 ]
Li, Sheng [1 ]
Zheng, HuiJuan [1 ]
Wang, Hao [1 ]
Liu, JingBing [1 ]
Li, KunWei [2 ]
Yan, Hui [1 ]
机构
[1] Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
[2] China Natl Inst Standardizat, Beijing 100088, Peoples R China
关键词
La2Ti2O7; Graphene; Nanocomposite; Photocatalytic properties; GRAPHENE OXIDE; REDUCTION; OXIDATION; SULFIDE; WATER;
D O I
10.1016/j.cej.2011.10.062
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Graphene-La2Ti2O7 nanocomposites used as photocatalyst were prepared via a two-step process in this paper. Graphite oxide was firstly exfoliated via thermal expanding process under 1000 degrees C, then the expanded graphite was reduced by La2Ti2O7 nanosheets under UV light irradiation. The as-prepared graphene-La2Ti2O7 nanocomposites were characterized by scanning electron microscopy (SEM), powder X-ray diffraction (XRD), BET surface area analyzer, Raman spectroscopy, Fourier transformation infrared (FTIR) spectroscopy and UV-vis diffuse spectroscopy. The composites exhibited an enhanced photocatalytic activity for decomposition of rhodamine B (RhB) under UV-irradiation compared to pure La2Ti2O7 materials, which was attributed to the increase in the charge separation efficiency in the presence of graphene and the large surface contact between graphene and La2Ti2O7. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:468 / 474
页数:7
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