Surface characterization of copper, zinc and brass in contact with tap water inhibited with phosphate ions

被引：24

作者：

Yohai, L. ^{[1
]}

Schreiner, W. H. ^{[2
]}

Vazquez, M. ^{[1
]}

Valcarce, M. B. ^{[1
]}

机构：

[1] UNMdP, Fac Ingn, INTEMA, Div Corros, Mar Del Plata, Buenos Aires, Argentina

[2] Univ Fed Parana, Dept Fis, Lab Superficies & Interfases, BR-81531990 Curitiba, PR, Brazil

来源：

APPLIED SURFACE SCIENCE | 2011年 / 257卷 / 23期

关键词：

Passive film; Copper; Zinc; Brass; Tap water; ELECTROCHEMICAL-BEHAVIOR; CORROSION INHIBITION; CHEMICAL-COMPOSITION; DRINKING-WATER; ANODIC FILMS; ALPHA-BRASS; CHLORIDE; SPECTROSCOPY; DISSOLUTION; SULFATE;

D O I：

10.1016/j.apsusc.2011.07.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

dThe composition of the surface layers has been investigated on copper, zinc and brass in contact with moderately hard, highly carbonated and chloride rich artificial tap water (ATW). Cyclic voltammetry, reflectance spectroscopy, X-ray diffraction, Raman spectroscopy and X-ray photoelectron spectroscopy have been used to identify the changes in composition that result from the incorporation of sodium orthophosphate to ATW. The results showed that when PO43- is added, the film changes its composition and it also becomes thinner, denser and more compact. On copper, the presence of CuO in the passive film can be correlated to the improvement in the corrosion behavior in the presence of phosphate ions. In the case of brass, the development of a thinner, compact and less porous Zn-3(PO4)(2) layer hinders Cu(I) dissolution. A mechanism explaining the effect of this inhibitor is proposed, which accounts for the experimental results. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：10089 / 10095

页数：7

共 48 条

[1] THE EFFECT OF PHOSPHATES ON THE SUSCEPTIBILITY OF ALPHA-BRASS TO STRESS-CORROSION CRACKING IN SODIUM-NITRITE [J].

ASHOUR, EA ;

ATEYA, BG .

CORROSION SCIENCE, 1995, 37 (03) :371-380

[2]

Babic R, 2001, J ELECTROCHEM SOC, V148, pB146, DOI 10.1149/1.1354608

[3]

Bell I. M., 1998, Raman Spectroscopic Library of Natural and Synthetic Pigments

[4] Quantitative Chemical State XPS Analysis of First Row Transition Metals, Oxides and Hydroxides [J].

Biesinger, Mark C. ;

Payne, Brad P. ;

Hart, Brian R. ;

Grosvenor, Andrew P. ;

McIntryre, N. Stewart ;

Lau, Leo W. M. ;

Smart, Roger St. C. .

PROCEEDINGS OF THE 17TH INTERNATIONAL VACUUM CONGRESS/13TH INTERNATIONAL CONFERENCE ON SURFACE SCIENCE/INTERNATIONAL CONFERENCE ON NANOSCIENCE AND TECHNOLOGY, 2008, 100

[5] Comparison of the spontaneous and anodic processes during dissolution of brass [J].

Burzynska, L .

CORROSION SCIENCE, 2001, 43 (06) :1053-1069

[6] X-ray photoelectron spectroscopy study on the chemical composition of copper tarnish products formed at low humidities [J].

Cano, E ;

López, MF ;

Simancas, J ;

Bastidas, JM .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (01) :E26-E30

[7] Properties of the passive films present on copper and copper-nickel alloys in slightly alkaline solutions [J].

Ceré, S ;

Vázquez, M .

JOURNAL OF MATERIALS SCIENCE LETTERS, 2002, 21 (06) :493-495

[8] The influence of the chemical composition of drinking water on cuprosolvency by biofilm bacteria [J].

Critchley, MM ;

Cromar, NJ ;

McClure, NC ;

Fallowfield, HJ .

JOURNAL OF APPLIED MICROBIOLOGY, 2003, 94 (03) :501-507

[9] DIFFERENCE REFLECTANCE SPECTROSCOPY OF ANODIC FILMS ON COPPER AND COPPER BASE ALLOYS [J].

DESANCHEZ, SR ;

BERLOUIS, LEA ;

SCHIFFRIN, DJ .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1991, 307 (1-2) :73-86

[10] Microstructure characterization of phase transformations in a Zn-22 wt%Al-2 wt%Cu alloy by XRD, SEM, TEM and FIM [J].

Dorantes-Rosales, HJ ;

López-Hirata, VM ;

Méndez-Velázquez, JL ;

Saucedo-Muñoz, ML ;

Hernández-Silva, D .

JOURNAL OF ALLOYS AND COMPOUNDS, 2000, 313 (1-2) :154-160

← 1 2 3 4 5 →