Highly efficient iron(III) molecular catalysts for solketal production

被引：32
作者：
Esposito, Roberto [1 ,2 ]
Cucciolito, Maria Elena [1 ,2 ]
D'Amora, Angela [1 ,2 ]
Di Guida, Rossella [1 ,2 ]
Montagnaro, Fabio [1 ]
Ruffo, Francesco [1 ,2 ]
机构：
[1] Univ Napoli Federico II, Dipartimento Sci Chim, Complesso Univ Monte S Angelo,Via Cintia 21, I-80126 Naples, Italy
[2] Consorzio Interuniv Reattivita Chim & Catalisi, Via Celso Ulpiani 27, I-70126 Bari, Italy
来源：
FUEL PROCESSING TECHNOLOGY | 2017年 / 167卷
关键词：
Iron; Solketal; Glycerol; Acetone; BIODIESEL PRODUCTION; ROOM-TEMPERATURE; GLYCEROL KETALIZATION; LEWIS-ACID; ACETONE; ACETALIZATION; CONVERSION; COMPLEXES; ZEOLITE;
D O I：
10.1016/j.fuproc.2017.08.018
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
This communication describes extremely efficient homogeneous iron(Ill) catalysts for the synthesis of solketal from glycerol and acetone. The activities are the highest ever reported so far for this type of reaction, with TOFs up to 10(5) h(-1) at negligible catalyst loading.
引用
收藏
页码：670 / 673
页数：4
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