Efficient dye-sensitized solar cells using electrospun TiO2 nanofibers as a light harvesting layer

被引:156
作者
Chuangchote, Surawut [1 ]
Sagawa, Takashi [1 ]
Yoshikawa, Susumu [1 ]
机构
[1] Kyoto Univ, Inst Adv Energy, Kyoto 6110011, Japan
关键词
D O I
10.1063/1.2958347
中图分类号
O59 [应用物理学];
学科分类号
摘要
Titanium dioxide (TiO2) nanofibers were fabricated directly onto thick nanoparticle electrodes by using electrospinning and sol-gel techniques. After calcination, the anatase TiO2 nanofibers obtained exhibited a one-dimensional structure of high crystallinity and average diameter of similar to 250 nm. Dye (N719) sensitized photoelectrochemical cells comprised of a nanoparticle/nanofiber electrode were fabricated. An IPCE of 85% at the wavelength of 540 nm with conversion efficiencies of 8.14% and 10.3% (for areas of 0.25 and 0.052 cm(2), respectively) were obtained under 1.5 AM (100 mW/cm(2)) illumination. (C) 2008 American Institute of Physics.
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页数:3
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共 19 条
[1]   Fabrication and optical properties of electrospun conductive polymer nanofibers from blended polymer solution [J].
Chuangchote, Surawut ;
Sagawa, Takashi ;
Yoshikawa, Susumu .
JAPANESE JOURNAL OF APPLIED PHYSICS, 2008, 47 (01) :787-793
[2]   Towards optimisation of electron transfer processes in dye sensitised solar cells [J].
Durrant, JR ;
Haque, SA ;
Palomares, E .
COORDINATION CHEMISTRY REVIEWS, 2004, 248 (13-14) :1247-1257
[3]   Spray deposition of electrospun TiO2 nanorods for dye-sensitized solar cell [J].
Fujihara, K. ;
Kumar, A. ;
Jose, R. ;
Ramakrishna, S. ;
Uchida, S. .
NANOTECHNOLOGY, 2007, 18 (36)
[4]   Conversion of sunlight to electric power by nanocrystalline dye-sensitized solar cells [J].
Grätzel, M .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2004, 164 (1-3) :3-14
[5]   Photoelectrochemical cells [J].
Grätzel, M .
NATURE, 2001, 414 (6861) :338-344
[6]   High-efficiency organic-dye-sensitized solar cells controlled by nanocrystalline-TiO2 electrode thickness [J].
Ito, Seigo ;
Zakeeruddin, Shaik M. ;
Humphry-Baker, Robin ;
Liska, Paul ;
Charvet, Raphael ;
Comte, Pascal ;
Nazeeruddin, Mmad K. ;
Pechy, Peter ;
Takata, Masakazu ;
Miura, Hidetoshi ;
Uchida, Satoshi ;
Graetzel, Michael .
ADVANCED MATERIALS, 2006, 18 (09) :1202-+
[7]   Multi-core cable-like TiO2 nanofibrous membranes for dye-sensitized solar cells [J].
Kokubo, Hiroshi ;
Ding, Bin ;
Naka, Takayuki ;
Tsuchihira, Hiroki ;
Shiratori, Seimei .
NANOTECHNOLOGY, 2007, 18 (16)
[8]   Electron transport properties in ZnO nanowire array/nanoparticle composite dye-sensitized solar cells [J].
Ku, Chen-Hao ;
Wu, Jih-Jen .
APPLIED PHYSICS LETTERS, 2007, 91 (09)
[9]   Nanowire dye-sensitized solar cells [J].
Law, M ;
Greene, LE ;
Johnson, JC ;
Saykally, R ;
Yang, PD .
NATURE MATERIALS, 2005, 4 (06) :455-459
[10]   Fabrication of titania nanofibers by electrospinning [J].
Li, D ;
Xia, YN .
NANO LETTERS, 2003, 3 (04) :555-560