Aquathermolysis of heavy oil in reservoir conditions with the use of oil-soluble catalysts: part II - changes in composition of aromatic hydrocarbons

被引：16

作者：

Vakhin, Alexey V. ^{[1
]}

Mukhamatdinov, Irek I. ^{[1
]}

Aliev, Firdavs A. ^{[1
]}

Kudryashov, Sergey I. ^{[2
]}

Afanasiev, Igor S. ^{[2
]}

Petrashov, Oleg V. ^{[2
]}

Sitnov, Sergey A. ^{[1
]}

Chemodanov, Artyom E. ^{[1
]}

Varfolomeev, Mikhail A. ^{[1
]}

Nurgaliev, Danis K. ^{[1
]}

机构：

[1] Kazan Fed Univ, Inst Geol & Petr Technol, Kazan, Russia

[2] JSC Zarubezhneft, Moscow, Russia

来源：

PETROLEUM SCIENCE AND TECHNOLOGY | 2018年 / 36卷 / 22期

关键词：

aquathermolysis; aromatic hydrocarbons; catalyst; heavy oil; transition metals; HIGH-VISCOSITY OIL; ORGANIC-MATTER; CONVERSION; ASPHALTITE; PRODUCTS; IRON;

D O I：

10.1080/10916466.2018.1514412

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

This paper discusses aquathermolysis process of heavy crude oil from Boca de Jaruco reservoir, which is developed by CSS method. The catalysts based on cobalt, nickel, iron and cupper are used to intensify the in-situ conversion processes. The active form of catalysts generates after steam injection. In second part of work the conversion of aromatic hydrocarbons depending on thermo-catalytic conditions and composition of catalysts are investigated. The thermo-catalytic treatment destructs resin and asphaltene molecules. The destruction products transform into aromatic fractions. The correlation between the C4-phenanthrene/naphtabenzothiophen ratio and the yields of aromatics and resins are revealed. The increase in high-molecular aromatic hydrocarbon, particularly tetramethyl-phenanthrene content is observed. However, the content of heteroatom compounds such as naphtabenzothiophen is constant. Based on IR-spectroscopy, the changes in composition of aromatic fraction are revealed. The lowest value of aromaticity index is detected for experiments with only hydrogen donor (without catalysts) and for experiments with Ni-, Cu-based catalysts.

引用

页码：1850 / 1856

页数：7

共 21 条

[11]

[Кудряшов С.И. Kudryashov S.I.], 2017, [Нефтяное хозяйство, Neftyanoe khozyaistvo], P30, DOI 10.24887/0028-2448-2017-8-30-34

[12] Conversion of organic matter in the carbonaceous medium in the supercritical water [J].

Petrov, S. M. ;

Ibragimova, D. A. ;

Safiulina, A. G. ;

Kalorazi, B. Tohidi ;

Vakhin, A. V. ;

Okekwe, R. C. ;

Karalin, E. A. .

JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING, 2017, 159 :497-505

[13] Conversion Processes for High-Viscosity Heavy Crude Oil in Catalytic and Noncatalytic Aquathermolysis [J].

Petrukhina, N. N. ;

Kayukova, G. P. ;

Romanov, G. V. ;

Tumanyan, B. P. ;

Foss, L. E. ;

Kosachev, I. P. ;

Musin, R. Z. ;

Ramazanova, A. I. ;

Vakhin, A. V. .

CHEMISTRY AND TECHNOLOGY OF FUELS AND OILS, 2014, 50 (04) :315-326

[14]

[Ситнов С.А. Sitnov S.A.], 2016, [Нефтяное хозяйство, Neftyanoe khozyaistvo], P106

[15] Aquathermolysis of conventional heavy oil with superheated steam [J].

Song Guangshou ;

Zhou Tiyao ;

Cheng Linsong ;

Wang Yunxian ;

Tian Guoqing ;

Pi Jian ;

Zhang Zheng .

PETROLEUM SCIENCE, 2009, 6 (03) :289-293

[16] The use of a tartaric-Co(II) complex in the catalytic aquathermolysis of heavy oil [J].

Song, Shao-Fu ;

Guo, Zhen ;

Bai, Yun ;

Gu, Xue-Fan ;

Chen, Gang ;

Zhang, Jie ;

Li, Bian-qing ;

Zhang, Zhi-Fang .

PETROLEUM SCIENCE AND TECHNOLOGY, 2017, 35 (07) :661-666

[17] Aquathermolysis of crude oils and natural bitumen: chemistry, catalysts and prospects for industrial implementation [J].

Tumanyan, B. P. ;

Petrukhina, N. N. ;

Kayukova, G. P. ;

Nurgaliev, D. K. ;

Foss, L. E. ;

Romanov, G. V. .

RUSSIAN CHEMICAL REVIEWS, 2015, 84 (11) :1145-1175

[18] Aquathermolysis of High-Viscosity Oil in the Presence of an Oil-Soluble Iron-Based Catalyst [J].

Vakhin, A. V. ;

Sitnov, S. A. ;

Mukhamatdinov, I. I. ;

Onishchenko, Ya. V. ;

Feoktistov, D. A. .

CHEMISTRY AND TECHNOLOGY OF FUELS AND OILS, 2017, 53 (05) :666-674

[19] Thermal Transformation of the Mobile-Hydrocarbon Composition of Domanik Deposits of Volga-Ural Oil-and Gas-Bearing Province [J].

Vakhin, A. V. ;

Onishchenko, Ya. V. ;

Nazimov, N. A. ;

Kadyrov, R. U. .

CHEMISTRY AND TECHNOLOGY OF FUELS AND OILS, 2017, 53 (04) :511-519

[20] Chemical evaluation and kinetics of Siberian, north regions of Russia and Republic of Tatarstan crude oils [J].

Varfolomeev, Mikhail A. ;

Nagrimanov, Ruslan N. ;

Samatov, Aizat A. ;

Rakipov, Ilnaz T. ;

Nikanshin, Alexander D. ;

Vakhin, Alexey V. ;

Nurgaliev, Danis K. ;

Kok, Mustafa V. .

ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS, 2016, 38 (08) :1031-1038

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