An operationally simple base-catalyzed multi-component domino transformation: Stereoselective preparation of trisubstituted alkenes and 1,3-dienes

被引：8
作者：
Habib-Zahmani, H
Hacini, S
Bories, C
Faure, R
Rodriguez, J
机构：
[1] Univ Aix Marseille 3, UMR CNRS 6178, Equipe ReSo, Ctr St Jerome, F-13397 Marseille, France
[2] Univ Oran Es Senia, Fac Sci, Dept Chim, Organ Synth Lab, Oran 31000, Algeria
来源：
SYNTHESIS-STUTTGART | 2005年 / 13期
关键词：
multi-component domino reaction; one-pot synthesis; trisubstituted alkenes; 1,3-dienes;
D O I：
10.1055/s-2005-869979
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A versatile and operationally simple base-catalyzed multi-component domino reaction between alpha,beta-unsaturated carbonyl compounds, aldehydes, and alcohols is described, providing a new efficient, and stereoselective one-pot preparation of trisubstituted alkenes and 1,3-dienes.
引用
收藏
页码：2151 / 2156
页数：6
相关论文
共 42 条
[31]   A one-pot synthesis of (E)-α-bromo-α,β-unsaturated esters and their trifluoromethylation:: a general and stereoselective route to (E)-α-trifluoromethyl-α,β-unsaturated esters [J].
Qing, FL ;
Zhang, XG .
TETRAHEDRON LETTERS, 2001, 42 (34) :5929-5931
[32]   Novel functionalized trisubstituted allylboronates via Hosomi-Miyaura borylation of functionalized allyl acetates [J].
Ramachandran, PV ;
Pratihar, D ;
Biswas, D ;
Srivastava, A ;
Reddy, MVR .
ORGANIC LETTERS, 2004, 6 (04) :481-484
[33]  
Salaun J., 1986, Org. Synth, V64, P50
[34]   New synthetic methodologies for carbon-carbon double bond formation [J].
Shen, YC .
ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (09) :584-592
[35]   Utilisation of 1,3-dicarbonyl derivatives in multicomponent reactions [J].
Simon, C ;
Constantieux, T ;
Rodriguez, J .
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2004, 2004 (24) :4957-4980
[36]   A new multicomponent domino reaction of 1,3-dicarbonyl compounds: One-pot access to amino azabicyclo[3.3.1]nonanones and 1,6-hydronaphthyridines [J].
Simon, C ;
Lieby-Muller, F ;
Peyronel, JF ;
Constantieux, T ;
Rodriguez, J .
SYNLETT, 2003, (15) :2301-2304
[37]   A new multicomponent domino reaction of 1,3-dicarbonyl compounds:: One-pot access to polycyclic N/O-, N/S-, and N/N-aminals [J].
Simon, C ;
Peyronel, JF ;
Rodriguez, J .
ORGANIC LETTERS, 2001, 3 (14) :2145-2148
[38]   Novel synthesis of the ocular age pigment A2-E: New method for substituted pyridine synthesis via azaelectrocyclization [J].
Tanaka, K ;
Katsumura, S .
ORGANIC LETTERS, 2000, 2 (03) :373-375
[39]   New developments in the Peterson olefination reaction [J].
van Staden, LF ;
Gravestock, D ;
Ager, DJ .
CHEMICAL SOCIETY REVIEWS, 2002, 31 (03) :195-200
[40]  
Williams J. M. J., 1996, Preparation of Alkenes
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