Modelling the effect of pre-swelling on adsorption dynamics of dyes by chitosan derivatives

被引：38

作者：

Kyzas, George Z. ^{[1
]}

Lazaridis, Nikolaos K. ^{[1
]}

Kostoglou, Margaritis ^{[1
]}

机构：

[1] Aristotle Univ Thessaloniki, Sch Chem, Div Chem Technol, GR-54124 Thessaloniki, Greece

来源：

CHEMICAL ENGINEERING SCIENCE | 2012年 / 81卷

关键词：

Swelling dynamics; Modeling; Dyes; Adsorption; Chitosan adsorbents; Kinetics; BASIC-DYES; HYDROGELS; REMOVAL; KINETICS; BIOSORBENTS; WATER;

D O I：

10.1016/j.ces.2012.07.007

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

It is well known that chitosan-based materials serve as efficient adsorbents for dyes. This type of materials undergoes swelling with finite rate, when they are immersed in water, until to reach an equilibrium (steady state) volume. A problem that has been overlooked in the literature is the interaction between the two phenomena of swelling and adsorption. The characteristic times of two phenomena are comparable, so the swelling state of the adsorbent particle affects adsorption kinetics. In the present work, the interaction between these two phenomena is studied for several combinations of chitosan-based adsorbents and dyes, using experimental and theoretical tools. Several experiments for different polymeric adsorbents (chitosan derivatives) and dyes (reactive and basic) were performed. It is clearly shown that the adsorption kinetics are sensitive to the time of the adsorbent immersion in water. A unified swelling-adsorption model is developed. This model is shown to be able to describe/reproduce the experimental data and allow their proper interpretation in terms of physicochemical processes. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：220 / 230

页数：11

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