Unprecedented Selective Oxidation of Styrene Derivatives using a Supported Iron Oxide Nanocatalyst in Aqueous Medium

被引：73

作者：

Rajabi, Fatemeh ^{[1
]}

Karimi, Nafiseh ^{[2
]}

Saidi, Mohammad Reza ^{[2
]}

Primo, Ana ^{[3
]}

Varma, Rajender S. ^{[4
]}

Luque, Rafael ^{[4
,5
]}

机构：

[1] Payame Noor Univ, Dept Sci, Tehran, Iran

[2] Sharif Univ Technol, Dept Chem, Tehran, Iran

[3] Univ Politecn Valencia, Inst Tecnol Quim, UPV CSIC, Valencia 46022, Spain

[4] US EPA, Sustainable Technol Div, Natl Risk Management Res Lab, Cincinnati, OH 45268 USA

[5] Univ Cordoba, Dept Quim Organ, Cordoba 14014, Spain

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2012年 / 354卷 / 09期

基金：

美国国家科学基金会;

关键词：

alkene oxidation; aqueous phase chemistry; heterogeneous catalysis; supported iron oxide nanoparticles; HYDROGEN-PEROXIDE; MESOPOROUS MATERIALS; METAL NANOPARTICLES; PLATFORM MOLECULES; ORGANIC-SYNTHESIS; EPOXIDATION; EFFICIENT; WATER; H2O2; TRANSFORMATIONS;

D O I：

10.1002/adsc.201100630

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Iron oxide nanoparticles supported on mesoporous silica-type materials have been successfully utilized in the aqueous selective oxidation of alkenes under mild conditions using hydrogen peroxide as green oxidant. The supported catalyst could be easily recovered after completion of the reaction and reused several times without any loss in activity (no metal leaching observed during the reaction), constituting a facile and straightforward example of aqueous oxidation chemistry promoted by iron-based heterogeneous systems.

引用

页码：1707 / 1711

页数：5

共 39 条

[1] Fe(III) complex anchored SBA-15 is a new heterogeneous catalyst for the cleavage of aliphatic C=C bond of styrene and its derivatives [J].