Nano n-propylsulfonated γ-Fe2O3 as magnetically recyclable heterogeneous catalyst for the efficient synthesis of β-phosphonomalonates

被引：46

作者：

Sobhani, Sara ^{[1
]}

Parizi, Zahra Pakdin ^{[1
]}

Razavi, Nasrin ^{[1
]}

机构：

[1] Birjand Univ, Coll Sci, Dept Chem, Birjand 414, Iran

来源：

APPLIED CATALYSIS A-GENERAL | 2011年 / 409卷

关键词：

Nanomagnetic iron oxide; Heterogeneous catalyst; beta-phosphonomalonates; 1,3-propanesultone; STATE ANALOG INHIBITORS; SULFONIC-ACID; ALPHA; BETA-UNSATURATED NITRILES; ORGANOPHOSPHORUS CHEMISTRY; INTERPHASE CATALYST; CARBONYL-COMPOUNDS; ALKYL PHOSPHITES; NANOPARTICLES; CONDUCTIVITY; DERIVATIVES;

D O I：

10.1016/j.apcata.2011.09.039

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nano n-propylsulfonated gamma-Fe2O3 as a new sulfonated nanomagnetic iron oxide was synthesized directly through ring opening reaction of 1,3-propanesultone with nano magnetic gamma-Fe2O3 and used as magnetically recyclable heterogeneous catalyst for the efficient one-pot synthesis of beta-phosphonomalonates. The catalyst was easily isolated from the reaction mixture by magnetic decantation using an external magnet and reused at least five times without significant degradation in the activity. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：162 / 166

页数：5

共 49 条

[1] ORGANOPHOSPHORUS CHEMISTRY .16. THE REACTION OF FURFURYLIDENEMALONITRILE WITH ALKYL PHOSPHITES [J].

ABDOU, WM ;

KHIDRE, MD ;

MAHRAN, MR .

JOURNAL FUR PRAKTISCHE CHEMIE, 1990, 332 (06) :1029-1034

[2] RENIN INHIBITORS - SYNTHESIS OF TRANSITION-STATE ANALOG INHIBITORS CONTAINING PHOSPHORUS-ACID DERIVATIVES AT THE SCISSILE BOND [J].

ALLEN, MC ;

FUHRER, W ;

TUCK, B ;

WADE, R ;

WOOD, JM .

JOURNAL OF MEDICINAL CHEMISTRY, 1989, 32 (07) :1652-1661

[3] SYNTHESIS AND STRUCTURE-ACTIVITY-RELATIONSHIPS OF ANTIBACTERIAL PHOSPHONOPEPTIDES INCORPORATING (1-AMINOETHYL)PHOSPHONIC ACID AND (AMINOMETHYL)PHOSPHONIC ACID [J].

ATHERTON, FR ;

HASSALL, CH ;

LAMBERT, RW .

JOURNAL OF MEDICINAL CHEMISTRY, 1986, 29 (01) :29-40

[4]

Baylis E.K., 1984, J CHEM SOC, V1, P2845, DOI [DOI 10.1039/P19840002845, 10.1039/P19840002845]

[5]

BODALSKI R, 1972, TETRAHEDRON LETT, P4209

[6] Nerve agent destruction by recyclable catalytic magnetic nanoparticles [J].

Bromberg, L ;

Hatton, TA .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2005, 44 (21) :7991-7998

[7] Magnetic nanoparticle supported catalyst for atom transfer radical polymerization [J].

Ding, Shijie ;

Xing, Yangchuan ;

Radosz, Maciej ;

Shen, Youqing .

MACROMOLECULES, 2006, 39 (19) :6399-6405

[8]

ENDERS D, 2006, EUR J ORG CHEM, V2, P9

[9] REACTION OF ALKYL PHOSPHITES ON SOME DERIVATIVES OF MALONONITRILES [J].

FAHMY, AA ;

ISMAIL, NA ;

HAFEZ, TS .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1992, 66 (1-4) :201-205

[10]

FAN J, 2006, J EXP NANOSCI, V45, P7

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