Synthesis, Characterization, and Photoluminescence Properties of a Planar Copper Triazolate Coordination Polymer with Cyanide as Co-Ligand

被引：11

作者：

Zhu, Ai-Xin ^{[1
,2
]}

Xu, Quan-Qing ^{[1
]}

Liu, Feng-Yi ^{[1
]}

Qi, Xiao-Lin ^{[2
]}

机构：

[1] Yunnan Normal Univ, Fac Chem & Chem Engn, Kunming 650092, Peoples R China

[2] Sun Yat Sen Univ, Sch Chem & Chem Engn, MOE Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2011年 / 637卷 / 05期

关键词：

Copper; Coordination polymers; 1,2,4-Triazolate; Cyanides; Crystal structure; Luminescence; METAL-ORGANIC FRAMEWORKS; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURE; COMPLEXES; CHEMISTRY; NETWORKS; BEHAVIOR; DESIGN;

D O I：

10.1002/zaac.201000367

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new copper coordination polymer [Cu-3(CN)(dmtz)(2)] (1) (Hdmtz = 3,5-dimethyl-1,2,4-triazole) was solvothermally synthesized and characterized by IR spectroscopy, X-ray power diffraction, and single-crystal X-ray diffraction. The single-crystal diffraction analysis shows that compound 1 belongs to the orthorhombic space group Pmmn, and exhibits a 2D planar framework constructed by the ligand dmtz and cyanide anions, in which the cyanide anion was generated from in situ decomposition of acetonitrile. The photoluminescent study indicates that 1 emits strong blue-green luminescence with long emission lifetimes in the solid state at room temperature.

引用

页码：502 / 505

页数：4

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