Electrolytic partial fluorination of organic compounds.: Part 27.: Regioselective anodic monofluorination of 2-substituted 1,3-dithiolanon-4-ones using Et4NF•4HF and Et3N•3HF

被引：22

作者：

Fuchigami, T ^{[1
]}

Narizuka, S

Konno, A

Momota, K

机构：

[1] Tokyo Inst Technol, Dept Elect Chem, Midori Ku, Yokohama, Kanagawa 226, Japan

[2] Shizuoka Univ, Fac Engn, Hamamatsu, Shizuoka 432, Japan

[3] Morita Chem Ind Co Ltd, Dept Res & Dev, Yodogawa Ku, Osaka 532, Japan

来源：

ELECTROCHIMICA ACTA | 1998年 / 43卷 / 14-15期

关键词：

anodic fluorination; 1,3-dithiolanone; regioselectivity; stereoselectivity; Et4NF center dot 4HF; Et3N center dot 3HF;

D O I：

10.1016/S0013-4686(97)10122-0

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Highly regioselective anodic monofluorination of 2-substituted 1,3-dithiolan-4-ones was successfully carried out by using novel supporting electrolyte, Et4NF . 4HF while a conventional supporting electrolyte, Et3N . 3HF gave poor yields and/or low current efficiencies owing to severe passivation of the anode during the electrolysis. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：1985 / 1989

页数：5

共 26 条

[1]

[Anonymous], 1991, Fluorine in Bioorganic Chemistry

[2] ELECTROCHEMICAL MONOFLUORINATION OF PYRIDINE - SYNTHESIS OF 2-FLUOROPYRIDINE AT A PLATINUM ANODE [J].