Statistical Copolymers of Methyl Methacrylate and 2-Methacryloyloxyethyl Ferrocenecarboxylate: Monomer Reactivity Ratios, Thermal and Electrochemical Properties

被引：15

作者：

Droulia, Margarita ^{[1
]}

Anastasaki, Athina ^{[1
]}

Rokotas, Alexandros ^{[1
]}

Pitsikalis, Marinos ^{[1
]}

Paraskevopoulou, Patrina ^{[2
]}

机构：

[1] Univ Athens, Dept Chem, Ind Chem Lab, Athens 15771, Greece

[2] Univ Athens, Dept Chem, Inorgan Chem Lab, Athens 15771, Greece

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2011年 / 49卷 / 14期

关键词：

2-methacryloyloxyethyl ferrocenecarboxylate; copolymerization; electrochemical properties; methyl methacrylate; radical polymerization; reactivity ratios; thermal properties; ORGANOMETALLIC POLYMERS; RADICAL COPOLYMERIZATION; TRANSITION-TEMPERATURES; DIBLOCK COPOLYMERS; POLYMERIZATION; STYRENE; POLY(FERROCENYLSILANE); DEGRADATION; DENDRIMERS; ACRYLATE;

D O I：

10.1002/pola.24745

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Statistical copolymers of methyl methacrylate (MMA) with 2-methacryloyloxyethyl ferrocenecarboxylate (MAEFC) were prepared by free radical polymerization. The reactivity ratios were estimated using the Fineman-Ross, inverted Fineman-Ross, Kelen-Tudos, and extended Kelen-Tudos graphical methods. Structural parameters of the copolymers were obtained by calculating the dyad monomer sequence fractions and the mean sequence length. The glass-transition temperature (T-g) values of the copolymers were measured and examined by means of several theoretical equations, allowing the prediction of these T-g values. The thermal degradation behavior of the copolymers was also studied and compared with the respective homopolymers. Cyclic voltammetry was employed to study the electrochemical properties of the copolymers. (C) 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 49: 3080-3089, 2011

引用

页码：3080 / 3089

页数：10

共 62 条

[1] Organometallic polymers of the transition metals [J].

Abd-El-Aziz, AS .

MACROMOLECULAR RAPID COMMUNICATIONS, 2002, 23 (17) :995-1031

[2] A NOVEL SYNTHETIC PROCEDURE OF VINYLACETAMIDE AND ITS FREE-RADICAL POLYMERIZATION [J].

AKASHI, M ;

YASHIMA, E ;

YAMASHITA, T ;

MIYAUCHI, N ;

SUGITA, S ;

MARUMO, K .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1990, 28 (12) :3487-3497

[3] Recent Progress in the Synthesis and Applications of Some Ferrocene Derivatives and Ferrocene-Based Polymers [J].

Amer, Wael A. ;

Wang, Li ;

Amin, Abid M. ;

Ma, Liang ;

Yu, Haojie .

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2010, 20 (04) :605-615

[4] Assembly of dendrimers with redox-active [{CpFe(μ3-CO)}4] clusters at the periphery and their application to oxo-anion and adenosine-5′-triphosphate sensing [J].

Aranzaes, JR ;

Belin, C ;

Astruc, D .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (01) :132-136

[5]

BARTON JM, 1970, J POLYM SCI POL SYM, P573

[6] RADICAL POLYMERIZATION OF 2-AMINOMETHYLMETHACRYLATES WITH METHYLMETHACRYLATE [J].

CAMAIL, M ;

ESSAOUDI, H ;

MARGAILLAN, A ;

VERNET, JL .

EUROPEAN POLYMER JOURNAL, 1995, 31 (11) :1119-1125

[7] Redox-active ferrocenyl dendrimers and polymers in solution and immobilised on electrode surfaces [J].

Casado, CM ;

Cuadrado, I ;

Morán, M ;

Alonso, B ;

García, B ;

González, B ;

Losada, J .

COORDINATION CHEMISTRY REVIEWS, 1999, 185-6 :53-79

[8] Multisite inclusion complexation of redox active dendrimer guests [J].

Castro, R ;

Cuadrado, I ;

Alonso, B ;

Casado, CM ;

Moran, M ;

Kaifer, AE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (24) :5760-5761

[9] Templated Self-Assembly of Square Symmetry Arrays from an ABC Triblock Terpolymer [J].

Chuang, Vivian P. ;

Gwyther, Jessica ;

Mickiewicz, Rafal A. ;

Manners, Ian ;

Ross, Caroline A. .

NANO LETTERS, 2009, 9 (12) :4364-4369

[10]

Coote ML, 1998, J MACROMOL SCI R M C, VC38, P567

← 1 2 3 4 5 6 7 →