Study of the ternary system germanium-antimony-tin: experimental phase diagram

被引:17
作者
Dichi, E
Wojakowska, A
Legendre, B
机构
[1] Univ Paris 11, Lab Chim Phys Minerale & Bioinorgan, EA 401, Fac Pharm, F-92296 Chatenay Malabry, France
[2] Med Acad, Lab Chim Minerale, PL-50139 Wroclaw, Poland
关键词
germanium; antimony; tin; phase equilibrium; ternary system; thermal analysis;
D O I
10.1016/S0925-8388(00)01489-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The phase diagram of the ternary system Ge-Sb-Sn was established by X-ray powder diffraction and differential scanning calorimetry. No ternary compound was found. Two vertical sections were studied in order to follow the reaction path. Four ternary reactions were characterised: three transition peritectic (U-type) reactions and one eutectoid (E-type) reaction. Moreover, from all equilibrium temperatures, a description of liquidus surface in the whole composition range is proposed. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:218 / 223
页数:6
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