A new lawsone azo-dye for optical sensing of Fe3+ and Cu2+ and their DFT study

被引：11
|
作者：
Sonawane, Mahendra [1 ]
Tayade, Kundan [1 ]
Sahoo, Suban K. [2 ]
Sawant, Chatur P. [3 ]
Kuwar, Anil [1 ]
机构：
[1] North Maharashtra Univ, Sch Chem Sci, Jalgaon, India
[2] SV Natl Inst Technol, Dept Appl Chem, Surat, India
[3] GT Patil Coll, Dept Chem, Nandurbar, India
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2016年 / 69卷 / 18期
关键词：
Chemosensor; lawsone azo-dye; Cu2+; Fe3+; FLUORESCENT SENSORS; IRON; MECHANISMS; COPPER; CHEMOSENSOR; TOXICITY; RECEPTOR;
D O I：
10.1080/00958972.2016.1210801
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new lawsone-based azo-dye 2-hydroxy-3-((pyridin-2-ylmethyl)diazenyl) naphthalene-1,4-dione (1) was synthesized and applied for sensing of metal ions. Receptor 1 showed selective fluorescent and colorimetric response for the detection of Cu2+ and Fe3+ over other tested metal ions. The fluorescence intensity of 1 was significantly quenched allowing detection of Fe3+ and Cu2+ down to 0.61 and 6.06 mu M, respectively. The binding has been established by fluorescence spectroscopic method. Receptor 1 provided a 1 : 1 binding scaffold for recognition of Fe3+ and Cu2+ ions with the association constant of 3.33 x 10(6) and 3.33 x 10(5) M-1, respectively. The B3LYP/6-31G/LANL2DZ method was employed for the optimization of 1 and 1.Fe3+ and 1.Cu2+. [GRAPHICS]
引用
收藏
页码：2785 / 2792
页数：8
相关论文
共 50 条
  • [1] Aldazine-based colorimetric sensors for Cu2+ and Fe3+
    Narayanaswamy, Nagarjun
    Govindaraju, T.
    SENSORS AND ACTUATORS B-CHEMICAL, 2012, 161 (01): : 304 - 310
  • [2] A new fluorescent chemosensor for Fe3+ and Cu2+ based on calix[4]arene
    Liu, JM
    Zheng, QY
    Yang, JL
    Chen, CF
    Huang, ZT
    TETRAHEDRON LETTERS, 2002, 43 (50) : 9209 - 9212
  • [3] A lawsone azo dye-based fluorescent chemosensor for Cu2+ and its application in drug analysis
    Sonawane, Mahendra
    Sahoo, Suban K.
    Singh, Jasminder
    Singh, Narinder
    Sawant, Chatur P.
    Kuwar, Anil
    INORGANICA CHIMICA ACTA, 2015, 438 : 37 - 41
  • [4] A fluorescent sensor for Cu2+ and Fe3+ based on multiple mechanisms
    He, Wei
    Liu, Zheng
    RSC ADVANCES, 2016, 6 (64) : 59073 - 59080
  • [5] A Colorimetric and Fluorescent Probe Based on Rhodamine B for Detection of Fe3+ and Cu2+ Ions
    Yan, Liqiang
    Xie, Ya
    Li, Jianping
    JOURNAL OF FLUORESCENCE, 2019, 29 (05) : 1221 - 1226
  • [6] The Amidine Based Colorimetric Sensor for Fe3+, Fe2+, and Cu2+ in Aqueous Medium
    Nandre, Jitendra
    Patil, Samadhan
    Patil, Prashant
    Sahoo, Suban
    Redshaw, Carl
    Mahulikar, Pramod
    Patil, Umesh
    JOURNAL OF FLUORESCENCE, 2014, 24 (06) : 1563 - 1570
  • [7] Visual-Detection of Cu2+ in DMSO aAqueous Solution Based on Benzimidazole Azo-dye as a Colorimetric Chemosensor
    Ghorbanian, Moein
    Asghari, Sakineh
    Tajbakhsh, Mahmood
    CHEMISTRYSELECT, 2024, 9 (31):
  • [8] Effect of Cu2+ and Fe3+ on the depression of molybdenite in flotation
    Yang, Bingqiao
    Wang, Deru
    Wang, Tianshuai
    Zhang, Hanquan
    Jia, Feifei
    Song, Shaoxian
    MINERALS ENGINEERING, 2019, 130 : 101 - 109
  • [9] A New Rhodamine B-coumarin Fluorochrome for Colorimetric Recognition of Cu2+ and Fluorescent Recognition of Fe3+ in Aqueous Media
    Tang, Lijun
    Li, Fangfang
    Liu, Minghui
    Nandhakumar, Raju
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2011, 32 (09) : 3400 - 3404
  • [10] One Single Molecule as a Multifunctional Fluorescent Probe for Ratiometric Sensing of Fe3+, Cr3+ and Colorimetric Sensing of Cu2+
    Yang, Yanqiu
    Yu, Kangkang
    Yang, Liang
    Liu, Jun
    Li, Kun
    Luo, Shunzhong
    SENSORS, 2015, 15 (01): : 49 - 58
12345