Four-step reduction of dpp-bian with sodium metal: Crystal structures of the sodium salts of the mono-, di-, tri- and tetraanions of dpp-bian

被引：195

作者：

Fedushkin, IL ^{[1
]}

Skatova, AA ^{[1
]}

Chudakova, VA ^{[1
]}

Fukin, GK ^{[1
]}

机构：

[1] Russian Acad Sci, GA Razuvaev Inst Organomet Chem, Nizhnii Novgorod 603950, Russia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 28期

关键词：

N ligands; polyanions; reduction; sodium; structure elucidation;

D O I：

10.1002/anie.200351408

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

One ligand, four anions! Four anionic forms of a single ligand bis[N-(2,6-diiso-propylphenyl)imino]acenaphthene (dpp-bian) were isolated on a preparative scale for the first time and unambiguously characterized by single-crystal X-ray structure analysis. The ligand, dpp-bian, may be easily reduced in diethyl ether by sodium metal to give the mono-, di-, tri-, or tetranion (depicted).

引用

页码：3294 / 3298

页数：5

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