Enhanced operational stability of the up-conversion fluorescence in films of palladium-porphyrin end-capped poly(pentaphenylene)

被引：62
作者：
Baluschev, S
Jacob, J
Avlasevich, YS
Keivanidis, PE
Miteva, T
Yasuda, A
Nelles, G
Grimsdale, AC
Müllen, K
Wegner, G
机构：
[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany
[2] Sony Deutschand GmbH, Mat Sci Lab, D-70327 Stuttgart, Germany
来源：
CHEMPHYSCHEM | 2005年 / 6卷 / 07期
关键词：
electron transfer; fluorescence; photochemistry; polymers; porphyrins;
D O I：
10.1002/cphc.200500098
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Up-conversion photoluminescence in a blue-emitting polymer doped with porphyrin macrocycles has been investigated and the component distribution of this system has been optimised. Covalent binding of the porphyrins to the polymer was implemented to decrease the separation of the dopant and matrix molecules, as well as dopant aggregation. The result is an up-conversion process with highly enhanced efficiency and operational stability (see picture; I=intensity). (Graph Presented) © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：1250 / 1253
页数：4
相关论文
共 8 条
[1]   Upconversion photoluminescence in poly(ladder-type-pentaphenylene) doped with metal (II)-octaethyl porphyrins -: art. no. 061904 [J].
Baluschev, S ;
Keivanidis, PE ;
Wegner, G ;
Jacob, J ;
Grimsdale, AC ;
Müllen, K ;
Miteva, T ;
Yasuda, A ;
Nelles, G .
APPLIED PHYSICS LETTERS, 2005, 86 (06) :1-3
[2]   Ladder-type pentaphenylenes and their polymers:: Efficient blue-light emitters and electron-accepting materials via a common intermediate [J].
Jacob, J ;
Sax, S ;
Piok, T ;
List, EJW ;
Grimsdale, AC ;
Müllen, K .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (22) :6987-6995
[3]   Up-conversion photoluminescence in polyfluorene doped with metal (II)-octaethyl porphyrins [J].
Keivanidis, PE ;
Baluschev, S ;
Miteva, T ;
Nelles, G ;
Scherf, U ;
Yasuda, A ;
Wegner, G .
ADVANCED MATERIALS, 2003, 15 (24) :2095-+
[4]   REGIOSPECIFIC ARYL NITRATION OF MESO-SUBSTITUTED TETRAARYLPORPHYRINS - A SIMPLE ROUTE TO BIFUNCTIONAL PORPHYRINS [J].
KRUPER, WJ ;
CHAMBERLIN, TA ;
KOCHANNY, M .
JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (11) :2753-2756
[5]   Controlling the response characteristics of luminescent porphyrin plastic film sensors for oxygen [J].
Mills, A ;
Lepre, A .
ANALYTICAL CHEMISTRY, 1997, 69 (22) :4653-4659
[6]   NEW OXYGEN SENSORS AND THEIR APPLICATION TO BIOSENSING [J].
PAPKOVSKY, DB .
SENSORS AND ACTUATORS B-CHEMICAL, 1995, 29 (1-3) :213-218
[7]  
Samoc A, 2002, POL J CHEM, V76, P345
[8]  
SEMEIKIN AS, 1986, CHEM HETEROCYCL COMP, V22, P397
1