AlBr3•6H2O catalyzed oxidation of benzylic alcohols

被引：7
作者：
Zhong, Yun-Mei [1 ]
Ma, Heng-Chang [1 ]
Wang, Jin-Xia [1 ]
Jia, Xiao-Jie [1 ]
Li, Wen-Feng [1 ]
Lei, Zi-Qiang [1 ]
机构：
[1] NW Normal Univ, Key Lab Polymer Mat Gansu Prov, Key Lab Ecoenvironm Related Polymer Mat, Coll Chem & Chem Engn,Minist Educ, Lanzhou 730070, Peoples R China
来源：
CATALYSIS SCIENCE & TECHNOLOGY | 2011年 / 1卷 / 06期
基金：
中国国家自然科学基金;
关键词：
TRANSITION-METAL-FREE; AEROBIC OXIDATION; MOLECULAR-OXYGEN; N-BROMOSUCCINIMIDE; CARBONYL-COMPOUNDS; HYDROGEN-PEROXIDE; IONIC LIQUID; EFFICIENT; ALDEHYDES; WATER;
D O I：
10.1039/c1cy00165e
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
AlBr3 center dot 6H(2)O was found to be an efficient catalyst in the field of oxidation of benzylic alcohols. Primary and secondary benzylic alcohols could be transformed into corresponding aldehydes and ketones with almost complete conversion and high selectivity. The non-transition metal related reaction systems have an incomparable advantage over others, such as easy work-up, excellent selectivity as well as commercial availability.
引用
收藏
页码：927 / 931
页数：5
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