Iridium-catalyzed ortho-C-H Borylation of Aryl Ketones with Bis(pinacolato)diboron

被引：46

作者：

Itoh, Hiroshi ^{[1
]}

Kikuchi, Takao ^{[1
]}

Ishiyama, Tatsuo ^{[1
]}

Miyaura, Norio ^{[1
]}

机构：

[1] Hokkaido Univ, Div Chem Proc Engn, Grad Sch Engn, Sapporo, Hokkaido 0608628, Japan

来源：

CHEMISTRY LETTERS | 2011年 / 40卷 / 09期

关键词：

DIRECTED ORTHO BORYLATION; ROOM-TEMPERATURE; BOND FUNCTIONALIZATION; HETEROARENES; ARENES; PINACOLBORANE; COMPLEXES; ESTERS;

D O I：

10.1246/cl.2011.1007

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

ortho-Selective C-H borylation of aryl ketones with bis(pinacolato)diboron proceeded at 120 degrees C in octane in the presence of a catalytic amount of iridium(I) complexes comprising 1/2[Ir(OMe)(cod)](2) and AsPh3.

引用

页码：1007 / 1008

页数：2

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