Optimizing Hydrogen Sensing Behavior by Controlling the Coverage in Pd Nanoparticle Films

被引:42
|
作者
Xie, Bo [1 ,3 ]
Liu, Linlin [1 ,3 ]
Peng, Xing [1 ,3 ]
Zhang, Yue [1 ,3 ]
Xu, Qian [1 ,3 ]
Zheng, Mengyang [1 ,3 ]
Takiya, Toshio [2 ]
Han, Min [1 ,3 ]
机构
[1] Nanjing Univ, Natl Lab Solid State Microstruct, Nanjing 210093, Peoples R China
[2] Hitachi Zosen Corp, Osaka 5510022, Japan
[3] Nanjing Univ, Dept Mat Sci & Engn, Nanjing 210093, Peoples R China
关键词
SINGLE PALLADIUM NANOWIRES; ELECTRICAL-CONDUCTION; MESOWIRE ARRAYS; SENSORS; SIZE; ABSORPTION; SWITCHES;
D O I
10.1021/jp2033752
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The response of quantum-conductance-based hydrogen sensors fabricated by controllable deposition of closely spaced Pd nanoparticle films between interdigital electrodes was investigated. Three typical response regions with different conductance-hydrogen pressure correlations were observed. The response characteristics of the devices were found to depend strongly on the nanoparticle coverage. In the low H(2) pressure region, higher coverage gives higher sensitivity. In the high H(2) pressure region, quantitative sensing can only be realized with low nanoparticle coverage. Optimizing the coverage allows the attainment of highly sensitive hydrogen sensors with a very wide quantitative working range, extending far beyond the hydrogen pressure region associated with the alpha-to-beta phase transition of Pd.
引用
收藏
页码:16161 / 16166
页数:6
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