A Cationic N-Heterocyclic Carbene with an Organometallic Backbone: Synthesis and Reactivity

被引：48
|
作者：
Hildebrandt, Bjoern [1 ]
Frank, Walter [1 ]
Ganter, Christian [1 ]
机构：
[1] Univ Dusseldorf, Inst Anorgan Chem, D-40225 Dusseldorf, Germany
来源：
ORGANOMETALLICS | 2011年 / 30卷 / 13期
关键词：
TRANSITION-METAL-COMPLEXES; BENZIMIDAZOLIN-2-YLIDENE LIGANDS; ELECTRONIC-PROPERTIES; PALLADIUM COMPLEXES; NHC LIGANDS; CATALYSIS; ACTIVATION; N; N'-DIAMIDOCARBENE; APPROXIMATION; AMMONIA;
D O I：
10.1021/om2004496
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new type of cationic N-heterocyclic carbene ligand has been developed by attachment of a cationic organometallic [(CsMes)Ru](+) fragment to a benzimidazolium cation and subsequent deprotonation of the dicationic sandwich complex. The coordination chemistry and electronic properties of the new carbene were investigated by experimental and theoretical methods.
引用
收藏
页码：3483 / 3486
页数：4
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