Synthesis and photophysical properties of multimetallic gold/zinc complexes of (P,N,N,N,P) and (P,N,N) ligands

被引：2
|
作者：
Walg, Simon P. [1 ]
Dietrich, Fabian [2 ,3 ,4 ,5 ]
Grun, Anneken [2 ,3 ]
Kucukdisli, Merve Cayir [1 ]
Sun, Yu [1 ]
Thiel, Werner R. [2 ,3 ]
Gerhards, Markus [1 ]
机构：
[1] Tech Univ Kaiserslautern, Inst Inorgan Chem, Erwin Schrodinger Str 54, D-67663 Kaiserslautern, Germany
[2] Tech Univ Kaiserslautern, Inst Phys & Theoret Chem, Erwin Schrodinger Str 52, D-67663 Kaiserslautern, Germany
[3] Tech Univ Kaiserslautern, Reseach Ctr Optimas, Erwin Schrodinger Str 52, D-67663 Kaiserslautern, Germany
[4] Univ La Frontera, Nucleo Milenio Multimat, Francisco Salazar 01145, Chile
[5] Univ La Frontera, Dept Ciencias Fis, Francisco Salazar 01145, Chile
来源：
NEW JOURNAL OF CHEMISTRY | 2022年 / 46卷 / 09期
关键词：
GOLD(I) COMPLEXES; CRYSTAL-STRUCTURE; METAL-COMPLEXES; LUMINESCENT GOLD(I); ELECTROCHEMISTRY; OXIDATION; ALKYNYL; COORDINATION; PHOTOCHEMISTRY; AUROPHILICITY;
D O I：
10.1039/d1nj05806a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Novel ligands carrying bipyridine and terpyridine analogue motifs were synthesized. These N-donor sites were linked to phosphine moieties with alkyl chains of defined lengths allowing heterobi- and -trimetallic complexes to be obtained. The orthogonal coordination behavior of the donor centers is proved by their selectivity in coordinating zinc(ii) as a hard and gold(i) as a soft Lewis acid. The ligands and complexes obtained in this manner were characterized by means of spectroscopic methods and X-ray structure analysis. Their photophysical properties were explored by measuring electronic absorption and fluorescence spectra as well as fluorescence lifetimes and were compared with the results of DFT calculations, all analyzed taking into account the issue of cooperativity.
引用
收藏
页码：4062 / 4071
页数：11
相关论文
共 50 条
  • [31] Synthesis, Structure, and Biological Activity of N-p-(Dimethylamino)-N′-(p-dimethylaminobenzylidene)-N,N′′-diphenylbenzohydrazonohydrazide
    Stalinskaya, A. L.
    Shulgau, Z. T.
    Sergazy, Sh D.
    Gulyaev, A. E.
    Turdybekov, D. M.
    Turdybekov, K. M.
    Kulakov, I., V
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2022, 92 (02) : 147 - 153
  • [32] Synthesis, Structure, and Biological Activity of N-p-(Dimethylamino)-N′-(p-dimethylaminobenzylidene)-N,N′′-diphenylbenzohydrazonohydrazide
    A. L. Stalinskaya
    Z. T. Shulgau
    Sh. D. Sergazy
    A. E. Gulyaev
    D. M. Turdybekov
    K. M. Turdybekov
    I. V. Kulakov
    Russian Journal of General Chemistry, 2022, 92 : 147 - 153
  • [33] Synthesis and crystal structure of zinc complex with N,N"-bis(p-carboxyphenyl-aminocarbonylmethyl)-N,N′,N"-trihydroxycarbonylmethyl diethylenetriamine
    Liu, YC
    Ma, SL
    Zhang, J
    Zhu, WX
    Xu, MQ
    ACTA CHIMICA SINICA, 2005, 63 (15) : 1397 - 1401
  • [34] Rhodium(I) and iridium(I) complexes with bidentate N, N and P, N ligands as catalysts for the hydrothiolation of alkynes
    Burling, S
    Field, LD
    Messerle, BA
    Khuong, QV
    Turner, P
    DALTON TRANSACTIONS, 2003, (21) : 4181 - 4191
  • [35] Chiral P,N,N-Ligands for Asymmetric Hydrogenation
    Liang, Ding-Hua
    Hou, Chuan-Jin
    Li, Qi
    Qin, Hao
    Li, Ling
    Hu, Xiang-Ping
    ADVANCED SYNTHESIS & CATALYSIS, 2024, 366 (10) : 2165 - 2185
  • [36] Material and n-p junction properties of N-, P-, and N/P-implanted SiC
    Gardner, JA
    Edwards, A
    Rao, MV
    Papanicolaou, N
    Kelner, G
    Holland, OW
    Capano, MA
    Ghezzo, M
    Kretchmer, J
    JOURNAL OF APPLIED PHYSICS, 1998, 83 (10) : 5118 - 5124
  • [37] INFLUENCE OF UNIAXIAL PRESSURE ON PROPERTIES OF p + -n-n + AND p + -n-p + SILICON STRUCTURES.
    Sultanov, N.A.
    Usmanov, K.U.
    1600, (09):
  • [38] Synthesis and characterization of new chiral Rh(I) complexes with N,N'-, and N,P-ligands. A study of anchoring on the modified zeolites and catalytic properties of heterogenized complexes
    J Organomet Chem, 1 (11):
  • [39] Convenient and improved protocols for the hydrogenation of esters using Ru catalysts derived from (P,P), (P,N,N) and (P,N,O) ligands
    Carpenter, Ian
    Eckelmann, Susan C.
    Kuntz, Michael T.
    Fuentes, Jose A.
    France, Marcia B.
    Clarke, Matthew L.
    DALTON TRANSACTIONS, 2012, 41 (34) : 10136 - 10140
  • [40] P-N-P-N SWITCHING PERFORMANCE OF N-P-N TRANSISTORS IN INTEGRATED-CIRCUITS
    NISHIMOTO, Y
    PROCEEDINGS OF THE IEEE, 1975, 63 (04) : 723 - 724
12345